| 光谱学与光谱分析 |
|
|
|
|
|
| Study on Experiment of Absorption Spectroscopy Detection of Pesticide Residues of Carbendazim in Orange Juice |
| JI Ren-dong1, 2, CHEN Meng-lan1, ZHAO Zhi-min1, 3*, ZHU Xing-yue1, WANG Le-xin1, LIU Quan-jin1，3 |
1. Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
2. Huaiyin Institute of Technology, Huai’an 223003, China
3. Jiangsu Key Laboratory of Spectral Imaging & Intelligent Sense, Nanjing 210094, China |
|
|
|
|
Abstract Absorption spectra were studied for the carbendazim, in the mixed solution of orange juice and carbendazim using spectrophotometer. The most intensive characteristic peak (285 nm) was found in the spectrum of carbendazim standard solution. Compared with the carbendazim drug solution, the peak position of absorption spectrum has the blue shift(285～280 nm)when carbendazim(0.28 mg·mL-1)was added in the orange juice. So that we can conclude that interaction happened between the orange juice and carbendazim. Through the method of least squares fitting, the prediction models between the absorbance of orange juice and carbendazim content was obtained with a good linear relationship. The linear function model was: I=2.41+9.26x, the correlation coefficient was 0.996, and the recovery was: 81%～102%. According to the regression model, we can obtain the amount of carbendazim pesticide residues in orange juice. It was verified that the method of using ultraviolet-visible absorption spectra was feasible to detect the carbendazim residues in orange juice. The result proved that it is possible to detect pesticide residues of carbendazim in orange juice, and it can meet the needs of rapid analysis. This study provides a new way for the detection of pesticide residues.
|
|
Received: 2013-05-23
Accepted: 2013-08-11
|
|
|
|
Corresponding Authors:
ZHAO Zhi-min1
E-mail: zhaozhimin@nuaa.edu.cn
|
|
[1] Nida’ M Salem, Rafat Ahmad, Hussein Estaitieh. Chemosphere, 2009，77：673.
[2] Jin Soo Park, Sun Kyoung Shin, Woo Il Kim, et al. Atmospheric Environment, 2011，45：7496.
[3] JI Ren-dong，ZHAO Zhi-min，ZHANG Lin, et al(季仁东，赵志敏，张 林，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2013，33(3)：668.
[4] ZHAO Ke-hua, CHE Jun, HUANG An-tai, et al(赵克华，车 军，黄安太，等). Hubei Agricultural Sciences(湖北农业科学)，2010，49(5)：1193.
[5] LI Jian-ke，WU Li-hua，KONG Xiang-hong(李建科，吴丽华，孔祥虹). Scientia Agricultura Sinica(中国农业科学)，2008, 41(6)：1767.
[6] Jose M C, Aan V, Guillermo S M, et al. Food Chemistry, 2009, 113: 280.
[7] Ting Keh-Chuh, Gerald S Tamashiro. Journal of Chromatography A, 1996，754：455.
[8] Eiki Watanabe, Koji Baba, Heesoo Eun, et al. Food Chemistry, 2007, 102: 745.
[9] TANG Bin(汤 斌). Based on Optical Spectroscopy for Detection of Pesticide Residues in Technology Research(基于光纤光谱技术农药残留分析测量方法研究). Chongqing: Chongqing University of Technology(重庆：重庆理工大学)，2010.
[10] ZHOU Ming-cheng, YU Ru-qin(周名成，俞汝勤). UV and Visible Spectrophotometric Method(紫外与可见分光光度分析法). Beijing: Chemical Industry Press(北京：化学工业出版社)，1986. |
| [1] |
ZHENG Pei-chao, YIN Yi-tong, WANG Jin-mei*, ZHOU Chun-yan, ZHANG Li, ZENG Jin-rui, LÜ Qiang. Study on the Method of Detecting Phosphate Ions in Water Based on
Ultraviolet Absorption Spectrum Combined With SPA-ELM Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 82-87. |
| [2] |
HUANG Xiao-wei1, ZHANG Ning1, LI Zhi-hua1, SHI Ji-yong1, SUN Yue1, ZHANG Xin-ai1, ZOU Xiao-bo1, 2*. Detection of Carbendazim Residue in Apple Using Surface-Enhanced Raman Scattering Labeling Immunoassay[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1478-1484. |
| [3] |
WANG Jin-mei, HE Shi, ZHANG Hang-xi, YANG Chen, YIN Yi-tong, ZHANG Li, ZHENG Pei-chao*. Study on the Detection Method of Nitrate Nitrogen in Water Based on
Ultraviolet Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1037-1042. |
| [4] |
HAO Jie, DONG Fu-jia, WANG Song-lei*, LI Ya-lei, CUI Jia-rui, LIU Si-jia, LÜ Yu. Rapid Detection of Pesticide Residues on Navel Oranges by Fluorescence Hyperspectral Imaging Technology Combined With Characteristic Wavelength Selection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3789-3796. |
| [5] |
HUANG Li-ying, CHEN Quan-li*, GAO Xin-xin, DU Yang, XU Feng-shun. Study on Composition and Spectral Characteristics of Turquoise Treated by “Porcelain-Added”[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2245-2250. |
| [6] |
CUI You-wei1,2, ZHENG Pei-chao1, WANG Xiao-fa1, JIAO Lei-zi2,3, DONG Da-ming1,2*, WU Jing2*. Trace Pesticide Measurement Method Based on Immunosensor and Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2275-2278. |
| [7] |
YANG Jun1，QI Li-mei1*，WU Li-qin2，LAN Feng3，LAN Chu-wen4,5，TAO Xiang1，LIU Zi-yu1. Research Progress of Terahertz Metamaterial Biosensors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1669-1677. |
| [8] |
ZHENG Pei-chao, ZHAO Wei-neng, WANG Jin-mei*, LAI Chun-hong, WANG Xiao-fa, MAO Xue-feng. Detection of COD UV Absorption Spectra Based on PSO-PLS Hybrid Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 136-140. |
| [9] |
HOU Yao-bin1, 2, FENG Wei-wei1, 2*, CAI Zong-qi1, WANG Huan-qing1, LIU Zeng-dong3. Nitrate Measurement in the Ocean Based on Neural Network Model[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3211-3216. |
| [10] |
BI Wei-hong1,2, FAN Jun-bo1,2, LI Zhe1,2, LI Yu1,2, WANG Si-yuan1,2, WANG Hao1,2, FU Guang-wei1,2, ZHANG Bao-jun1,2. In-Situ Measurement of Total Organic Carbon Concentration in Seawater Based on Ultraviolet Absorption Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(08): 2484-2489. |
| [11] |
ZHANG Nan, ZHUANG Ling-hua. Spectral Analysis and Structural Identification of Remifentanil Acid[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(07): 2059-2065. |
| [12] |
TIAN Guang-jun1, XU Guang-yao1, TIAN Qing2. A Piecewise Mathematical Model for COD Measurement of Water by UV Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1741-1746. |
| [13] |
CHEN Xiao-wei1,2,3, YIN Gao-fang1,3, ZHAO Nan-jing1,3*, GAN Ting-ting1,2,3, YANG Rui-fang1,3, ZHU Wei1,2,3, LIU Jian-guo1,3, LIU Wen-qing1,3. Study on the Determination of Nitrate with UV First Derivative Spectrum under Turbidity Interference[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(09): 2912-2916. |
| [14] |
ZHU Cong-hai1, 3, CHEN Guo-qing1, 3*, ZHU Chun1, 2, 3, ZHAO Jin-chen1, 3, LIU Huai-bo1, 3, ZHANG Xiao-he1, 3, SONG Xin-shu1, 3. Studies of the Fluorescence Properties of Methanol and Ethanol Based on the Density Functional Theory[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1133-1138. |
| [15] |
LIU Fei1, 2, DONG Da-ming1*, ZHAO Xian-de1, ZHENG Pei-chao2*. Online Measurement of Water COD-A Comparison between Ultraviolet and Near Infrared Spectroscopies[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2724-2729. |
|
|
|
|
