光谱学与光谱分析 |
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XPS and UPS Characterization for Cr and Mn in High-Temperature Oxide Films of Bulk Nanocrystalline 304 Stainless Steel |
XU Song-ning1, WANG Sheng-gang2*, HAN Hai-bao1, 3, SUN Nai-kun1 |
1. School of Science, Shenyang Ligong University, Shenyang 110159, China 2. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China 3. College of Information, Shanxi Agricultural University, Taigu 030800, China |
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Abstract The authors studied the binding energies of valence electrons of two oxide scales, the atomic percentages of Cr and Mn elements in two oxide films, the work function of two oxide films on bulk nanocrystalline 304 stainless steel (BN-SS304) and conventional polycrystalline 304 stainless steel (CP-SS304). BN-SS304 was prepared by severe rolling technique, and the two oxide films were formed in atmosphere at 900 ℃ for 24 hours oxidation on BN-SS304 and CP-SS304 surfaces. In the two oxide films, Cr and Mn elements exist in the forms of Cr3+, Cr0, Mn4+ and Mn0. The atomic percentage ratios of Cr3+ / (Cr3+ +Cr0) and Mn4+/ (Mn4++Mn0) in the oxide film on BN-SS304 are lower than those in the oxide film on CP-SS304. The interactions of the two oxides and the valence electrons of elements are Mn—O,Cr—O,3d and 4s of Mn0 and Cr0. The binding energies of the valence electrons in the oxide film on BN-SS304 are larger than those in the oxide film on CP-SS304, the work function of the oxide film on BN-SS304 is 0.07 eV larger than that on CP-SS304.
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Received: 2012-07-19
Accepted: 2012-11-20
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Corresponding Authors:
WANG Sheng-gang
E-mail: sgwang@imr.ac.cn
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[1] LI Mei-shuan(李美栓). High Temperature Corrosion of Metal(金属的高温腐蚀). Beijing: Metallurgical Industry Press(北京: 冶金工业出版社),2001. 120. [2] Vesel A, Mozetic M, Drenic A. Applied Surface Science, 2008, 255 (5): 1759. [3] Sujittra Daengsakul, Chunpen Thomas, Charusporn Mongkolkachit. Solid State Sciences, 2012, 14(9): 1306. [4] La Peiqing, Wang Hongding, Bai Yaping. Materials Science and Engineering: A, 2011, 528(21): 6489. [5] Dariusz Moszyński, Izabela Moszyńska, Walerian Arabczyk. Materials Letters, 2012, 78: 32. [6] Khinlay M, James C E, Farghalli A M. Acta Materialia, 2012, 60(16): 5850. [7] Wang S G, Shen C B, Long K. Phys. Chem. B, 2005, 109: 2499. [8] Wang S G, Sun M, Cheng P C. Materials Chemistry and Physics, 2011, 127: 459. [9] Nie F L, Wang S G, Wang Y B. Dental Materials, 2011, 2(7): 677. [10] SUN Miao(孙 淼). Corrosion Behavior of Bulk Nanocrystalline 304 Stainless Steel (纳米晶304不锈钢的腐蚀行为研究). Shenyang: Shenyang University of Technology(沈阳:沈阳工业大学), 2010. [11] Ghods P, Isgor O B, Brown J R. Applied Surface Science, 2011, 257(10): 4669. [12] Nesbitt H W, Bancroft G M, Henderson G S. Journal of Non-Crystalline Solids, 2011, 357(1):170. [13] Speranza G, Torrengo S, Miotello A. Diamond and Related Materials, 2011, 20(4): 560. [14] Li Xiangli, Qi Hanhong. Physics Procedia, 2012, 25: 1048. [15] Ildo L S, Hédio Tatizawa, Francisco A M. Energy Policy, 2012, 41: 885. |
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