光谱学与光谱分析 |
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Gd-Doped Natural Thenardite∶Eu Photoluminescence Properties of Europium |
Guzaliayi JUMAN, Tuerxun AIDILIBIKE, Aizitiaili ABULIZI, Aierken SIDIKE* |
School of Physics and Electronic Engineering, Xinjiang Normal University, Urumqi 830054, China |
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Abstract The authors prepared Na2SO4∶Eu, Gd, and Na2Gd2(SO4)4∶Eu phosphors by heating, the mixed powder of GdF3, EuF3 and natural mirabilite with muffle furnace at 1 000 ℃ for 30 min and continually heating it with microwave at 750 ℃ for 10 min. With increasing the concentrations of Gd ion, the 610 nm emission intensity due to Eu3+ was strengthened. Gd3+ probably formed a bridge between substrate and the activator so that the energy is able to be transferred efficiently. The luminescence intensity, along with colorimetric purity, reaches the top with 21 mol% Gd3+ doping in the thenardite (Na2SO4∶Eu) lattices, eventually coming up the quenching effects of concentration.
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Received: 2011-12-11
Accepted: 2012-03-16
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Corresponding Authors:
Aierken SIDIKE
E-mail: aierkenjiang@sina.com
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