| 光谱学与光谱分析 |
|
|
|
|
|
| Spectral Property of One-Dimensional Rodlike Nano Cellulose |
| ZHANG Li-ping1, TANG Huan-wei1, QU Ping1, LI Shuai1, QIN Zhu2, SUN Su-qin2 |
1. College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, China
2. Department of Chemistry, Tsinghua University, Beijing 100084, China |
|
|
|
|
Abstract The object of the present paper was researching a kind of nano cellulose prepared by the pretreatment of diluted acid and the physical method of high pressure homogenization. The cellulose pulp was pretreated by diluted acid and then prepared by high pressure homogenization. The one-dimensional rodlike nano cellulose was obtained. And the spectral properties of nano cellulose were characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The thermal property of nano cellulose was analyzed by thermogravimetric analysis (TGA). The dimension and morphology of nano celluose were observed using atomic force microscope (AFM) and transmission electron microscopy (TEM). FTIR analysis results showed that the one-dimensional rodlike nano cellulose had the same characteristic functional groups as cellulose pulp. And it was showed that intramolecular hydrogen bond association effects of nano cellulose were partly destroyed. It was indicated by XRD analysis that nano cellulose and cellulose pulp corresponded to the crystal type of cellulose Ⅰ. The crystallinity of nano cellulose was increased from 59% to 70%, compared to cellulose pulp. Nano cellulose still maintained both crystalline domains and amorphous regions, although crystalline domains and amorphous regions were partly damaged by preparing process. Thermal analysis results demonstrated that the thermal stability of nano cellulose was lower than that of cellulose pulp. The decomposition temperature of nano cellulose was 330 ℃. Two weight-loss stages were present in the range 292～500 ℃. The TEM photograph showed that nano cellulose was significantly rodlike shape with hundreds of nanometer in length and tens of nanometers in width. AFM image showed that nano cellulose was agglomerated together.
|
|
Received: 2009-12-06
Accepted: 2010-03-08
|
|
|
|
Corresponding Authors:
ZHANG Li-ping
E-mail: zhanglp418@163.com
|
|
[1] Zimmermann T, Phles E, Geiger T. Advanced Engineering Materials, 2004, 6：754.
[2] Sun D P, Zhou L L, Wu Q H, et al. Journal of Wuhan University of Technology- Materials Science Edition, 2007, 22：677.
[3] LI Qiu-jin, YIN You-li, SU Rong-xin, et al(李秋瑾, 殷友利, 苏荣欣, 等). Acta Chimica Sinica(化学学报), 2009, 67：88.
[4] Morán J I, Alvarez V A, Viviana P, et al. Cellulose, 2008, 15(1)：149.
[5] Goetz L, Mathew A, Oksman K, et al. Carbohydrate Polymers, 2009, 75(1)：85.
[6] Agblevor F A, Ibrahim M M, El-Zawawy W K. Cellulose, 2007, 14(3)：247.
[7] Andresen M, Johansson L S, Tanem B S, et al. Cellulose, 2006, 13(6)：665.
[8] YE Dai-yong(叶代勇). Process in Chemistry(化学进展), 2007, 19(10)：1568.
[9] Ganster J, Fink H P. Cellulose, 2006, 13(3)：271.
[10] Childress A E, Elimelech M. Journal of Membrane Science, 1996, 119(2)：253.
[11] Auad M L, Contos V S, Steve Nutt S, et al. Polym. Int., 2008, 57(4)：651.
[12] Matos R M, Cavaillé J Y, Dufresne A, et al. Composite Interfaces, 2000, 7(2)：117.
[13] Cheng Q Z, Wang S Q, Rials T G. Composites part A: Applied Science and Manufacturing, 2009, 40(2)：218.
[14] Nishino T, Takano K, Nakamae K. Journal of Polymer Science: Part B: Polymer Physics, 1995, 33(11)：1647.
[15] Beck-Candanedo S, Roman M, Gray D G. Biomacromolecules, 2005, 6(2)：1048.
[16] Lee S Y, Mohan D J, Kang I A, et al. Fibers and Polymers , 2009, 10(1)：77.
[17] ZHAO Yan, LI Dong, LU Wen-jin, et al(赵 岩, 李 冬，陆文静, 等). Acta Chimica Sinica(化学学报), 2008, 66(20)：2295.
[18] WANG Neng, DING En-yong, CHENG Rou-shi(王 能, 丁恩勇, 程镕时). Acta Polymerica Sinica(高分子学报), 2006, (8)：982.
[19] LI Guo-kang, DING En-yong, LI Xiao-fang, et al(黎国康, 丁恩勇, 李小芳, 等). Journal of Cellulose Science and Technology(纤维素科学与技术), 2002, 10(2)：12.
[20] Samir M, Alloin F, Paillet M, et al. Macromolecules, 2004, 37(11)：4313.
[21] CHENG Qing-zheng, WANG Si-qun(程庆正, 王思群). Chinese Forestry Products Industry(林产工业), 2007, 34(3)：3.
|
| [1] |
SUN Yan-wen1, CHANG Yu2, JIN Yu-fen1, XIE Wen-bing2, CHANG Jing1, YU Ting1*, PAN Li-hua2. Study of Synthesis and Spectral Property of Europium Cryptate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2189-2193. |
| [2] |
FAN Chun-hui1, CHANG Min1, ZHANG Ying-chao2 . Spectral Characteristics of Dissolved Organic Matter (DOM) Derived from Water and Sediment in Normal Flow Period of the Intersection Zone of Jing River and Wei River [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(09): 2863-2869. |
| [3] |
ZHA Jia-yu, LIN Ying-hui, XU Jun-chao, ZHANG You-lai, ZENG Lin-tao* . Synthesis and Spectroscopic Properties of Some Novel BODIPY Dyes [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(11): 3034-3039. |
| [4] |
YI Ying1, SONG Chun-feng1*, YUAN Hong-fu1, XIE Jin-chun1, DU Jun-qi2, LI Xiao-yu1 . Determination of Degree of Polymerization of Natural Cellulose Pulp Using Near-Infrared Diffuse Reflectance Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(09): 2372-2376. |
| [5] |
SHEN Xiao-min, JIANG Xiong-jie, ZHU Yu-jiao, ZHANG Han-hui, HUANG Jian-dong* . Spectral Properties, Photodynamic Anticancer Activity and the Interaction with Albumin of Silicon Phthalocyanine Axially Modified by Pyrimidine Derivatives [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(08): 2148-2152. |
| [6] |
QU Ping, WANG Xuan, CUI Xiao-xia, ZHANG Li-ping*. Biomimetic Mineralization of Rod-Like Cellulose Nano-Whiskers and Spectrum Analysis [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(05): 1418-1422. |
| [7] |
TAN Chao1, PENG Chun-xiu2, GAO Bin1, GONG Jia-shun1* . Spectroscopic and Structural Characteristics of the Main Components of Theabrownin in Pu-erh Tea [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(04): 1051-1056. |
| [8] |
XIAO Rong-ping，HUANG Jian-dong*，ZHANG Han-hui* . Synthesis and Spectroscopic Properties of Covalent Albumin Conjugates of Phthalocyanine Zincs Substituted with Metadicarboxyphenoxyl Groups [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(05): 1322-1327. |
| [9] |
XIAO Rong-ping，ZHANG Na，HUANG Jian-dong*，ZHANG Han-hui* . Influence of Albumin on the Spectroscopic Properties and Existence State of Mono-Substituted Phthalocyanine Zinc(Ⅱ) [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(04): 1052-1056. |
| [10] |
WU Ji-qing, ZHANG Tian-jin*, WANG Jing-yang, YU Lin, PAN Rui-kun . Spectroscopic Properties of Er3+∶Ba0.65Sr0.35TiO3 Nanopowders [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(11): 3107-3110. |
| [11] |
TANG Li-rong, HUANG Biao*, DAI Da-song, OU Wen, LIN Yan-ping, CHEN Xue-rong . Preparation and Spectrum Properties of Cellulose Nanoparticles [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(07): 1876-1879. |
| [12] |
GONG Jia-shun1, HU Xiao-jing1, PENG Chun-xiu2, ZHOU Hong-jie3 . The Molecular Composition and Spectral Properties of Polysaccharide Isolated from Pu-Erh Tea and Its Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(07): 1960-1964. |
| [13] |
XIONG Hui-xin, ZHOU Li-xiang*. Preparation of Nanocrystalline Goethite (α-FeOOH) by Gel-Network Precipitation Method and Spectral Properties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(06): 1590-1594. |
| [14] |
AI Shi-yun1,GAO Ji-gang1,ZHU Lu-sheng2*,MA Zhi-jun1,LI Xiao-chen1. Preparation and Spectroscopic Studies of Nanosilver/Silk-Fibroin Composite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(09): 2126-2129. |
| [15] |
LI Heng-da1,WANG Qing-wei1*,ZHAI Hong-ju1,LI Wen-lian1, 2. Properties of Synthesized CdS Nanoparticles by Reverse Micelle Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(07): 1573-1577. |
|
|
|
|
