| 光谱学与光谱分析 |
|
|
|
|
|
| Monitoring and Analysis of Vertical Profile of Atmospheric HONO, NO2 in Boundary Layer of Beijing |
| ZHU Yan-wu1, 4，LIU Wen-qing3，FANG Jing2，XIE Pin-hua3，DOU-ke3，QIN Min3，SI Fu-qi3 |
1. School of Chemical Engineering, Hefei University of Technology, Hefei 230009, China
2. School of Computer & Information, Hefei University of Technology, Hefei 230009, China
3. Key Lab of Environmental Optics and Technology, Chinese Academy of Sciences, and Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China
4. Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering, Hefei 230009, China |
|
|
|
|
Abstract Based on the scanning differential optical absorption spectroscopy (DOAS) system, field measurement of vertical profiles of HONO and NO2 was performed continuously from Aug. 27, 2007 to Sep. 4, 2007 in Chaoyang District of Beijing, and their vertical profiles were analyzed. Based on the acquired data, the typical vertical variation characteristics of HONO, NO2 and the ratio HONO/NO2 were discussed, and the possible formation sources of HONO were studied. The results indicated that the decrease of HONO with height was faster than the decrease of NO2. The study found good correlation between NO2 and HONO, as well as between the ratio HONO/NO2 and vapor, respectively. Therefore, the authors’ conclusion is that HONO was formed by heterogeneous conversion of NO2 on surfaces or near ground and then transported to higher altitudes.
|
|
Received: 2010-05-10
Accepted: 2010-08-20
|
|
|
|
Corresponding Authors:
ZHU Yan-wu
E-mail: yanwuzhu@sina.com
|
|
[1] HU Fei, HONG Zhong-xiang, LEI Xiao-en(胡 非, 洪钟祥, 雷孝恩). Chinese Journal of Atmospheric Sciences(大气科学), 2003, 27(4): 713.
[2] TANG Xiao-yan, ZHANG Yuan-hang, SHAO Min(唐孝炎，张远航，邵 敏). Atmospheric Environmental Chemistry. 2nd ed(大气环境化学, 第2版). Beijing: Higher Education Press(北京: 高等教育出版社), 2006. 221.
[3] WANG Ming-xing(王明星). Atmospheric Chemistry. 2nd ed(大气化学, 第2版). Beijing: China Meteorological Press(北京: 气象出版社), 1999. 165.
[4] Harwood E A, Hopkins P B, Sigurdsson S T. J. Org. Chem., 2000, 65: 2959.
[5] Pitts J N Jr. Envir Health Perspec., 1983, 47: 115.
[6] ZHU Yan-wu, XIE Pin-hua, DOU Ke, et al(朱燕舞, 谢品华, 窦 科, 等). Acta Optica Sinica(光学学报), 2009, 29(2): 297.
[7] ZHU Yan-wu, LIU Wen-qing, XIE Pin-hua, et al(朱燕舞, 刘文清, 谢品华, 等). Acta Photonica Sinica(光子学报), 2009, 38(8): 2040.
[8] ZHU Yan-wu, LIU Wen-qing, XIE Pin-hua, et al(朱燕舞, 刘文清, 谢品华, 等). Environmental Science(环境科学), 2009, 30(6): 1567.
[9] Wang S, Ackermann R, Stutz J. Atmos. Chem. Phys., 2006, 6: 2671.
[10] Kleffmann J, Kurtenbach R, Lrzer J, et al. Atmospheric Environment, 2003, 37: 2949.
[11] Wiesen P, Kleffmann J, Kurtenbach R. Faraday Discuss, 1995, 100: 121.
[12] Gereck A, Thielmann A, Gutzwiller L. Geophysical Research Letters, 1998, 25: 2453.
[13] Veitel H, Kromer B, Mirko M, et al. Environ. Sci. Pollut. Res., 2002, 4: 17.
[14] Lammel G, Cape J N. Chem. Soc. Rev., 1996, 25(5): 361.
[15] Alicke B, Platt U, Stutz J. J. Geophys. Res., 2002, 107(D22), 8196, doi: 10. 1029/2000JD000075.
|
| [1] |
CUI Song1, 2, BU Xin-yu1, 2, ZHANG Fu-xiang1, 2. Spectroscopic Characterization of Dissolved Organic Matter in Fresh Snow From Harbin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3937-3945. |
| [2] |
BI Yan-qi1, 2 , YANG Ying-dong3, DU Jing4, TANG Xiang5, LUO Wu-gan1, 2*. A Study on Mineral Material Sources of Multi-Style Bronzes Collected by Cultural Relic Administration Center of Huili County, Sichuan Province With MC-ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1140-1146. |
| [3] |
LIU Han-yang1, XING Cheng-zhi3*, JI Xiang-guang4, LIN Ji-nan3, ZHAO Chun-hui3, WEI Shao-cong2, ZHANG Cheng-xin2, LIU Hao-ran5, TAN Wei3, LIU Cheng2. Taking Juehua Island as a Typical Example to Explore the Vertical
Distribution Characteristics and Potential Sources of Air Pollutants[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 760-766. |
| [4] |
TIAN Xin1, 3, REN Bo3, 5, XIE Pin-hua1, 3, 4, 5, MOU Fu-sheng2*, XU Jin3, LI Ang3, LI Su-wen2, ZHENG Jiang-yi3LI Xiao-mei3, REN Hong-mei3, HUANG Xiao-hui1, PAN Yi-feng1, TIAN Wei1. Study on Vertical Distribution of Atmospheric HONO in Winter Based on Multi-Axis Differential Absorption Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2039-2046. |
| [5] |
WANG Cai-ling1, WANG Bo2, JI Tong3, XU Jun4, JU Feng5, WANG Hong-wei6*. Simulated Estimation of Nitrite Content in Water Based on
Transmission Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2181-2186. |
| [6] |
LIU Ji-fu1, YANG Ming-xing1*, SU Yue1, LIU Yue2. Analysis of Material and Source of Archaic Jade From the Tomb of Marquis Yi of Zeng in Suizhou, Hubei Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 215-221. |
| [7] |
JIANG Cheng1, TANG Gui-qian2*, LI Qi-hua1*, LIU Bao-xian3, WANG Meng2, WANG Yue-si2. Vertical Profile of Aerosol in Spring in Beijing Based on Multi-Axis Differential Optical Absorption Spectroscopy Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 265-271. |
| [8] |
LI Qing-bo1, HE Lin-qian1, CUI Hou-xin2, HAO Long-teng2, SUN Dong-sheng2. Determination of Nitrite Nitrogen Concentration in Surface Water Based on UV-Vis Spectral Analysis Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1127-1131. |
| [9] |
YANG Ze-ming1, 2, LI Cai1*, LU Gui-xin1, CAO Wen-xi1. A Study of Fast Detection of Nitrite in Seawater Based on Sequential Injection Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(02): 589-595. |
| [10] |
WANG Jing-min1, ZHANG Jing-chao1*, ZHANG Zun-ju1,2. Rapid Determination of Nitrate Nitrogen and Nitrite Nitrogen by Second Derivative Spectrophotometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(01): 161-165. |
| [11] |
WEI Guo-feng1, QIN Ying2*, WANG Le-qun3. Study on Copper Ores Source of Bronze Vessels in Zongyang County, Anhui Province, Dated from the Western Zhou Dynasty to Warring States Period[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3610-3615. |
| [12] |
CAO Ya-nan1,2, WANG Rui1，2, WANG Gui-shi1*, ZHU Gong-dong1, TAN Tu1*, WANG Jing-jing1，2, LIU Kun1, WANG Lei1, MEI Jiao-xu1, GAO Xiao-ming1. Development of High Precision Sun Tracker for the Application in Laser Heterodyne Radiometer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3626-3631. |
| [13] |
DONG Jun-qing1，SUN Guo-ping2, WANG Ning-yuan2, LOU Hang2, LI Qing-hui1*, GU Dong-hong1. Analysis the Neolithic Jade Jue Unearthed from Three Sites in Zhejiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2905-2913. |
| [14] |
YANG Yu-zhang1, ZENG Ling-yuan1*, WANG Fa-zhi2, CUI Wei2, XU Fan2, ZHANG Ju-zhong1. Chemical Compositions and Sources of Glaze-Making Technology of Bluish-White Glaze Fired at Fanchang Kiln, Anhui Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(04): 1009-1015. |
| [15] |
AN Xue-jing, LUO Yun-jing*, ZHANG Chen-yang. Research on the Reaction Dynamics between Peroxynitrite and Tyrosine Catalyzed with Mimic Enzyme through Flow Injection Analyzer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(12): 4052-4057. |
|
|
|
|
