| 光谱学与光谱分析 |
|
|
|
|
|
| Vibronic Coupling Parameters and Luminescent Properties of Bivalent Europium Ion Doped Alkaline Earth Thioaluminates |
| ZHANG Dong-pu, XUE Wei, YU Zhi-nong*, ZHANG Ting, JIANG Yu-rong, LENG Jian, KONG Xiang-jun |
| School of Optoelectronics, Beijing Institute of Technology, Beijing 100081, China |
|
|
|
|
Abstract To obtain blue and green electroluminescent phosphor of high efficiency, vibronic coupling parameters and luminescent properties of MⅡAl2S4∶Eu materials were researched. Configuration coordinate model, which is the base of assessment, was introduced and assessing parameters were listed firstly. Photoluminescent (PL) and electroluminescent (EL) properties of MⅡAl2S4∶Eu were compared and analyzed by the PL and EL spectra. Additionally, performances of MⅡAl2S4∶Eu phosphor materials were evaluated with the calculation of characteristic energy and unitless factors by PL spectra. According to the result of assessment and the comparison of CIE1931 color coordinates, it can be concluded that BaAl2S4∶Eu and CaAl2S4∶Eu are suitable for blue and green emitting phosphor. Mg and Sr thioaluminates can be used as parts of complex thioaluminate phosphors because they can shift the emission peaks.
|
|
Received: 2010-04-15
Accepted: 2010-07-18
|
|
|
|
Corresponding Authors:
YU Zhi-nong
E-mail: znyu@bit.edu.cn
|
|
[1] Donohue P C, Hanlon J E. Journal of the Electrochemical Society, 1974, 121(1): 137.
[2] Van Haecke J E, Smet P F, Poelman D. Journal of Luminescence, 2007, 126: 508.
[3] Yu Rui-jin, Wang Jing, Zhang Xin-min, et al. Chemistry Letters, 2008, 37(4): 410.
[4] Le Thi K T, Garcia A, Guillen F, et al. Material Science and Engineering B, 1992, 14(4): 393.
[5] Miura N, Kawanishi M, Matsumoto H, et al. Japanese Journal of Applied Physics Part 2, 1999, 38: 1291.
[6] Nazarov M, Tsukerblat B, Noh D Y. Journal of Physics and Chemistry of Solids, 2008, 69: 2605.
[7] Shionoya S, Yen W M. Phosphor Handbook, Boca Raton, FL: CRC Press, 1999.
[8] Blasse G, Grabmaier B C. Luminescent Materials, Berlin: Spinger, 1994.
[9] Wager J F. Journal of Luminescence, 2008, 128: 1851.
[10] Cheong D, Nakua A, Belluz P D B. 2002 SID International Symposium Digest of Technical Papers. USA, Palisades Convention Management Inc, 2002. 105.
[11] Yu Rui-jin, Wang Jing, Zhang Mei, et al. Journal of the Electrochemical Society, 2008, 155(10): J290.
[12] ZHANG Dong-pu, YU Zhi-nong, XUE Wei, et al. Journal of Rare Earths, 2010, 28(2): 185.
[13] Miura N. 2004 SID International Symposium Digest of Technical Papers. USA, Palisades Convention Management Inc, 2004. 1142.
[14] Liu G, Acchione J. 2006 SID International Symposium Digest of Technical Papers. USA, Palisades Convention Management Inc, 2006. 1308.
[15] Eisenmann B, Jakowski M, Klee W, et al. Revue de Chimie Minerale, 1983, 20: 255.
[16] Oh S K, Kim W T, Cho E J, et al. Journal of the Korean Physical Society, 1997, 31: 677.
[17] Eisenmann B, Jakowski M, Schaefer H. Materials Research Bulletin, 1982, 17: 1169.
[18] Eisenmann B, Jakowski M, Schaefer H. Materials Research Bulletin, 1984, 19: 77.
[19] LIU Quan-sheng, ZHANG Xi-yan, BAI Zhao-hui, et al(刘全生，张希艳，柏朝晖，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2009, 29(3): 769.
|
| [1] |
LAI Niu, HUANG Qi-qiang, ZHANG Qin-yang, ZHANG Bo-wen, WANG Juan, YANG Jie, WANG Chong, YANG Yu, WANG Rong-fei*. Introduction to Perovskite Quantum Dots and Metal-Organic Frameworks and the Development of Composites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3321-3329. |
| [2] |
ZHU Xiang1, 2, YUAN Chao-sheng2, LIANG Yong-fu2, WANG Zheng2, LI Hai-ning2, HUANGFU Zhan-biao1, ZHOU Song1, ZHOU Bo1, DONG Xing-bang1, CHENG Xue-rui2*, YANG Kun1*. Study on the Effect of Cooling Rate on Crystallization Process and
Product of [C12mim][BF4] Melt Based on POM, Raman and SAXS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 801-805. |
| [3] |
College of Information Science and Technology, Nanjing Forestry University, Nanjing 210037, China
. Investigation on Terahertz Spectroscopy of Food Additives Based on Dispersion-Correction Functional Theory[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 100-104. |
| [4] |
WANG Yu1, LUO Lan1, 2*, GUO Rui1, SUN Chuan-yao1, GAO Ming-yuan1. Cation Substitution-Dependent Phase Transition and Color-Tunable Emission in (Ca1-xBax)2SiO4∶Eu Phosphor Series[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1895-1901. |
| [5] |
ZHANG Hong1, WANG Le1*, LUO Dong1, ZHENG Zi-shan1, LI Yang-hui1, 2, PAN Gui-ming1. Structural and Luminescence Properties of Eu2+ Doped CaAlSiN3 Silicon Nitride Red Emitting Phosphor[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 59-64. |
| [6] |
LIN Qing-feng, ZHOU Liang-liang, SUN Yan-qiong*, CHEN Yi-ping. The Hydrothermal Synthesis, Crystal Structure and Spectral Properties of a 2D Pr-Cd Heterometal Complex[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(10): 3034-3039. |
| [7] |
PENG Chen-jia1, WANG Ke-hua1*, LU Wei-xue1, GUAN Chun-qian1, HU Ya-jing1, MA Shuang1, ZHU Ming-chang2, GAO En-jun2. Synthesis, Crystal Structure and DNA/BSA Interaction of a Ni(Ⅱ) Coordination Compound[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(02): 559-564. |
| [8] |
SU Ya-jing, FAN Ting-ting, ZHANG Mei-na, LI Xia*. 4,4’-Bipyridine Bridged Chain Zn(Ⅱ) Complex: Synthesis, Crystal Structure and Fluorescence Sensitization for Tb (Ⅲ) Ion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2170-2174. |
| [9] |
LI Rui, FAN Ting-ting, QU Xiang-long, DONG Gao-yun, LI Jia-jia, LI Xia*, SONG Yu-xin, ZHAO Xin-meng, LI Xiang . Fluorescence Properties and the Detection of Nitrobenzene of Lanthanides Complex with 3,4-Thiophenedicarboxylic Acid and 1,10 Phenanthroline[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(08): 2522-2526. |
| [10] |
WANG Xin-zhou1, 2, DENG Yu-he1*, WANG Si-qun2*, YU Wang-wang1, 3, HE Shuang-shuang1, ZHANG Jie1. Study on the Structure and Nanomechanical Properties of Organic Montmorillonite Reinforced Urea-Formaldehyde Adhesive[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(06): 1680-1684. |
| [11] |
GUO Zhen-qiang1, CHEN Yi-ping1, 2*, HUANG Meng-meng1, ZHOU Meng-qian1, SUN Yan-qiong1. The Hydrothermal Synthesis, Structure and Spectroscopy Study on (H2dap)6H[V12B16O54(OH)4]·12H2O(dap=1,2-diaminopropane)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(09): 2625-2628. |
| [12] |
MENG Zeng-rui1, 2, SHANG Li-ping3, DU Yu2, 4*, DENG Hu1 . Absorption Characteristics and Simulation of LLM-105 in the Terahertz Range [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(07): 1779-1782. |
| [13] |
FAN Ting-ting1, SONG Shuang1, 2, ZHANG Yi-hua1, 3, HUO Rui1, LI Xia1*, DING Xing-yi1, LIU Yang1, ZHAO Xu1, YAN Chun-hui1. Synthesis, Crystal Structure and Fluorescence Properties of Two Tb(Ⅲ) Complexes [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(07): 1917-1920. |
| [14] |
QIU Li-xia1, WAN Fang1, ZHU Bin-bin1, SUN Yan-qiong1,2*, YOU Yi1*, CHEN Yi-ping1 . Synthesis, Structure and Spectroscopy Study of a 1D Copper Coordination Polymer Based on a Carboxybenzyl Viologen Ligand and SCN-Anion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(05): 1340-1344. |
| [15] |
ZHANG Bao-yong1, 2, 3, LIU Chuan-hai2, 3*, WU Qiang2, 3, GAO Xia3, 4 . Raman Spectroscopic Studies on CO2—CH4—N2 Mixed-Gas Hydrate System[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(06): 1560-1565. |
|
|
|
|
