| 光谱学与光谱分析 |
|
|
|
|
|
| Near-Infrared Fluorescence and Energy Transfer in Sr2SiO4∶Eu2+,Nd3+ |
| YANG Li-li1，WAN Wen-jiao1，LI Jin-qing1，MENG Jian-xin2* |
1. Department of Chemistry, Jinan University, Guangzhou 510632，China
2. Institute of Nano-Chemistry, Jinan University, Guangzhou 510632，China |
|
|
|
|
Abstract Sr2SiO4∶Eu2+, Nd3+ was synthesized by solid state synthesis method, and the sensitization of Nd3+ near-infrared luminescence by Eu2+ was investigated. The characteristic near-infrared luminescence of Nd3+ in Sr2SiO4 matrix was greatly enhanced by co-doping of Eu2+. The mechanism of energy transfer from Eu2+ to Nd3+ was analyzed through investigation of fluorescence excitation and emission spectra, and fluorescence lifetime. Excited Eu2+(Ⅱ) transfers energy effectively to Nd3+ through non-radiative energy transfer process in Sr2SiO4, resulting in greatly enhanced near-infrared luminescence of Nd3+, while sensitization of Nd3+ by Eu2+(Ⅰ) was achieved by the way of Eu2+(Ⅱ).
|
|
Received: 2010-05-10
Accepted: 2010-08-20
|
|
|
|
Corresponding Authors:
MENG Jian-xin
E-mail: tmjx@jnu.edu.cn
|
|
[1] Driesen K, Deun R V, Walrand C G, et al. Chemistry of Materials, 2004, 16: 1531.
[2] Boyer J C, Manseau M P, Murray J I, et al. Langmuir, 2010, 26(2): 1157.
[3] Nishi M, Tanabe S, Inoue M, et al. Optical Materials, 2005, 27: 655.
[4] Sharma Y K, Surana S S L, Singh R K, et al. Optical Materials, 2007, 29: 598.
[5] Amarie D, Alileche A, Dragnea B, et al. Analytical Chemistry, 2010, 82: 343.
[6] Meng J X, Li J Q, Shi Z P, et al. Applied Physics Letters, 2008, 93: 221908.
[7] Meng J X, Cheah K W, Shi Z P, et al. Applied Physics Letters, 2007, 91: 151107.
[8] He H, Fu R L, Zhang X L, et al. Journal of Materials Science, 2009, 20: 433.
[9] Qiao Y M, Zhang X B, Ye X, et al. Journal of Rare Earths, 2009, 27(2): 323.
[10] Lakshminarasimhan N, Varadaraju U V. Materials Research Bulletin, 2008, 42: 2946.
[11] Kim J S, Jeon P E, Choi J C, et al. Solid State Communications, 2005, 133: 187.
[12] Sun X Y, Zhang J H, Zhang X, et al. Journal of Rare Earths, 2008, 26(3): 421.
[13] Lee J H, Kim Y J. Materials Science and Engineering B, 2008, 146: 99. |
| [1] |
ZHAN Ying-fei, LIU Chun-guang*, WANG Ming-wei, YANG Jian, ZHU Han-cheng, YAN Duan-ting, XU Chang-shan, LIU Yu-xue. Preparation, Microstructure and Optical Properties of Cr3+ Single-Doped and Eu3+/Cr3+ Co-Doped GdAlO3 Near Infrared Long Persistent Luminescent Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 80-87. |
| [2] |
ZHAO Yuan, LÜ Zhao-yue*, DENG Jian, ZENG Guo-qing. The Emissive Mechanism of C545T Thin Layer at the Exciplex and Non-Exciplex Interfaces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3711-3715. |
| [3] |
SUN Chuan-yao1, LUO Lan1, 2*, WANG Yu1, GUO Rui1, ZHANG Yuan-bo1. Photoluminscence Spectra and Ternary CIE Colour Image of (Mg1-x-yBaxSry)1.95SiO4∶0.05Eu Phosphor Series[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 98-106. |
| [4] |
ZHANG Yong1,2, ZHU Jin-ming1, YANG Li-li1*, Lü Shi-quan1, WU Yan-qun1，CHU Xue-juan1. Effect of Dy3+ on Luminescence Properties of Tb3+ Activated Silicate Oxyfluoride Scintillating Glass[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1412-1419. |
| [5] |
ZHENG Jia-jin1, 2, LU Qiang1, ZHENG Rui-lin1, ZOU Hui1, YU Ke-han1, WEI Wei1. Preparation and Photoluminescence Properties of Fluorophosphate Glasses with High Efficient White Light Emission[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(01): 39-44. |
| [6] |
CHEN Xiao-bo1, LI Song1, YU Chun-lei2, WANG Shui-feng1, ZHAO Guo-ying3, MA Hui1,ZHENG Dong1, YANG Guo-jian1, LIU Yuan1, DENG Zhi-wei1, HE Qing1, HU Li-li2. Intense Spectral Modulation by Quantum Cutting Luminescence of Er3+Yb3+ Ion-Pair in Nanophase Oxyfluoride Vitroceramics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1949-1957. |
| [7] |
ZHANG Chun-yan1,2, LUO Jian-xin2*, OU Li-juan2, LIU Yong2, HU Bo-nian2, YU Gui-peng1*, PAN Chun-yue1*. Luminescence Properties of Carbazole-Substituted Alq3 Derivative: a Potential Multifunctional Fluorescent Sensing Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1290-1297. |
| [8] |
CHEN Yue-e1, SHAO Qiu-feng2, JIA Li-xiao1. Judd-Ofelt Theory Analysis and Spectroscopic Properties of Nd3+-Doped Cadmium Aluminium Silicate Glasses[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1345-1349. |
| [9] |
WAN Ying，HE Jiu-yang, MA Yuan-yuan, ZHOU Zhi-xuan, Taximaiti·Yusufu, Aierken·Sidike*. Synthesis and Luminescence Properties of a New Type of Green Fluorescent Powder BaAl2Si2O8∶Tb3+, Ce3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1595-1600. |
| [10] |
FU Zhen-xing1, LIU Bi-rui1, YANG Bing-xiong2 . Spectroscopic Properties of Energy Transfer Effect in Sm3+/Eu3+ Doped LaF3 Nanocrystals [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(08): 2686-2691. |
| [11] |
JING Qiu-min1, LIU Sheng-gang1*, LIU Yong-gang2, BI Yan1 . Fluorescent Characteristics of Strontium Tetraborate (SrB4O7) Doped with Divalent Lanthanide Elements [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(01): 130-133. |
| [12] |
MA Yuan-yuan, HE Jiu-yang, Aziguli·Reheman, Bahadeer·Rouzi, Aierken·Sidike* . Photoluminescence of Sinthetic Scapolite Na4Ca4Al6Si9O24 Phosphors Activated with Ce3+ and Tb3+ and Energy Transfer from Ce3+ to Tb3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(11): 3241-3246. |
| [13] |
DONG Guo-shuai, LIU Hai-bo, LUO Li*, WANG Yin-hai . Study on Synthesis and Luminescence Mechanism of Novel Green Sr3Y(PO4)3∶Ce3+, Tb3+ Phosphors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(08): 2189-2193. |
| [14] |
CHEN Xiao-bo1, ZHOU Gu1, ZHOU Yong-fen2, WU Zheng-long1, GUO Yu-ying1, WANG Shui-feng1, ZOU Qiu-yan3, ZHUANG Jian4, 5, CHEN Xiao-duan1, LI Chun-mi1, YAO Wen-ting1, CHENG Huan-li1 . Near-Infrared Quantum Cutting Downconversion Luminescence of Yb3+ Ion Cooperative Energy Transferred from YVO4 Matrix Donor [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(02): 315-319. |
| [15] |
TONG Yi-ping, YAN Jia-yan . Syntheses and Luminescence Investigation of CaAl12O19：xMn4+ Red Phosphors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(12): 3210-3213. |
|
|
|
|
