光谱学与光谱分析 |
|
|
|
|
|
Comparative Research on Light-Induced Surface Electron Behavior of Cobalt Complexes |
LI Lei, JIN Jing, SHI Zhong-feng, XING Yong-heng, NIU Shu-yun* |
School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China |
|
|
Abstract Six cobalt complexes, Co(H2O)6·H2btec(1); {[Co2(HCOO)6]·CH3OH}n(2); {[Co(4,4’-bipy)2(H2O)4]·suc·4H2O}n(3); Co(NA)2(H2O)4(4); [Co(mal)(4,4’-bipy)H2O]n(5) and [Co(HCOO)4Co(H2O)4]n(6), were synthesized through hydrothermal method. UV-Vis absorption spectra and surface photovoltage spectra of the complexes were detected and the structures of the complexes were determined by single-crystal X-ray diffraction. There are positive responses in the range of 300-800 nm in the SPS. There are good corresponding relationships between response bands of SPS and absorption peaks of UV-Vis absorption spectra by the comparison. Comparing the SPS of six complexes, the valence, coordination mode and coordination micro-environment affect the position and the shape of the response bands.
|
Received: 2009-10-12
Accepted: 2010-01-16
|
|
Corresponding Authors:
NIU Shu-yun
E-mail: syniu@sohu.com
|
|
[1] Nayak M, Koner R, Evans H S, et al. Cryst. Growth Design., 2005, 5(5): 1907. [2] Shimazaki Y, Kabe R, Huth S, et al. Inorg. Chem., 2007, 46(15): 6083. [3] Kronik L, Shapira Y. Surf. Sci. Rep., 1999, 37: 1. [4] WANG De-jun, LIU Wang, XIAO Liang-zhi, et al(王德军,刘 旺,肖良质,等). Chin. Chem. Bull.(化学通报), 1989, (10): 32. [5] Sun Er-jun, Sun Zhao-yan, Yuan Mao, et al. Dyes and Pigments, 2009, 81(2): 124. [6] Sun Liping, Niu Shu-yun, Jin Jing, et al. Eur. J. Inorg. Chem., 2006: 5130. [7] ZHANG Li, NIU Shu-yun, JIN Jing, et al(张 丽,牛淑云,金 晶,等). Chin. Sci. Bull.(科学通报), 2008, 53(3): 339. [8] Zhang Li, Niu Shuyun, Jin Jing, et al. Inorg. Chim. Acta, 2009, 362: 1448. [9] Gibson V C, Redshaw C, Solan G A. Chem. Rev., 2007, 107(5): 1745. [10] Burda C, Chen Xiaobo, Narayanan R, et al. Chem. Rev., 2005, 105(4): 1025. [11] Fabelo O, Pasán J, Delgado L C, et al. Inorg. Chem., 2008, 47(18): 8053. [12] Wang Li-ya, Zhu Yu, Du Chen-xia, et al. J. Mol. Struct., 2002, 610(1-3): 191. [13] Wang Yanqin, Cao Rong, Bi Wenhua, et al. Microporous Mesoporous Mater., 2006, 91(1-3): 215. [14] Jin Jing, Niu Shu-yun, Yang Guang-di, et al. Z. Anorg. Allg. Chem., 2006, 632(14): 2350. [15] Cakir S, Bulut I, Naumov P, et al. J. Mol. Struct., 2001, 560(1-3): 1. [16] Lightfoot P, Snedden A. J. Chem. Soc. Dalton Trans., 1999. 3549. [17] Kaufman A, Afshar C, Rossi M, et al. Struct. Chem., 1993, 4(3): 191.
|
[1] |
DONG Xue1, QI Li-jian2, ZHOU Zheng-yu2, SUN Dui-xiong1*. Spectral Characteristics and Application of Synthetic Hydrothermal Red Beryl[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(02): 517-521. |
[2] |
LIU Xiao-zhen1, FENG Jun-liang1, LIU Xiao-zhou2, CHEN Jie3, ZHU Wan-wan1, GUI Xiu-min1 . Effect of REAu on Silver Staining Results and Their UV-Vis Absorption Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(12): 3560-3564. |
[3] |
HUANG Juan, ZHENG Chan, FENG Miao, ZHAN Hong-bing*. Kinetic Study on the In Situ Synthesis of Nickle Phthalocyanine in Silica Gel Glass Matrix by UV/Vis Absorption Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(01): 207-210. |
[4] |
KOU Jin. Synthesis, Structure and Surface Photovoltage Spectrum of Coordination Supramolecule: [Cu(phen)(H2O)2·SO4] [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(02): 361-365. |
[5] |
ZHEN Xiao, FENG Miao, ZHENG Chan, HUANG Juan, ZHAN Hong-bing*. Linear and Nonlinear Optical Properties of Zinc Phthalocyanines[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(02): 403-406. |
[6] |
ZHEN Xiao, FENG Miao, ZHENG Chan, HUANG Juan, ZHAN Hong-bing*. Photostability and Optical Limiting Cycling Behavior of Chloroindium (Ⅲ) Phthalocyanine [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(11): 2291-2293. |
[7] |
XUE Jin-ping, HONG Hu-ming, YE Ting-xiu, FAN Chang-an,SUN Gang-chun, CHEN Nai-sheng*, HUANG Jin-ling . Study on UV-Vis Absorption Spectra of Tetra-Azo-Aromaticoxy Substituted Metallophthalocyanines[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(11): 2050-2052. |
[8] |
LIU Wei,YE Tao,GUO Rong. Study on the Reaction between Cobalt Tetrasulphonated Phthalocyanine and Sodium Sulfide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(06): 762-767. |
|
|
|
|