光谱学与光谱分析 |
|
|
|
|
|
Collision-Induced Vibrational Energy Transfer: K2[11Σ+u(v′=2)]+He,H2→K2[11Σ+u(v′=1,3)]+He,H2 |
WANG Shu-ying1,2,LIU Jing2,DAI Kang2,SHEN Yi-fan2* |
1. School of Sciences,Xi’an Jiaotong University,Xi’an 710049,China 2. School of Physics,Xinjiang University,Urumqi 830046,China |
|
|
Abstract Collisional energy transfer processes K2[11Σ+u(v′=2)]+He,H2→K2[11Σ+u(v′=1,3)]+He,H2 were studied by laser induced fluorescence under gas cell conditions. During the experiments, the cell temperature was kept constant at 420K.The buffer gas pressure was varied over the range from 40 to 250 Pa, K2 molecules were irradiated with pulses of radiation from an OPO laser, populating K2[11Σ+u(v′=2)] by photon absorption. The resulting fluorescence included the direct component emitted in the decay of the optically excited state and the sensitized components arising from collisionally populated states. The decay signal of time-resolved fluorescence from 11Σ+u(v′=2)→11Σ+g(v″=0) transition was monitored. In the early period after excitation, only very little population in states v′=1 or 3 had yet accumulated, the rate of collisional activation to the state v′=2 was negligible. The decay curve of the v′=2→v″=0 was treated as a single exponential function. From the measurement of the time-resolved fluorescence, the semilog plot was shown. The slope yielded the effective lifetime of the v′=2→v″=0 transition. Based on the Stern-Volmer equation, the radiative lifetime (36±7) ns was obtained. The total cross sections for deactivation of 11Σ+u(v′=2) state by means of collisions with He and H2 are (3.0±0.5)×10-16 cm2 and (6.4±1.2)×10-15 cm2, respectively.The radiative lifetimes of 11Σ+u(v′=1,3) states can also be determined through time-resolved fluorescence in pure K vapor. The time-integrated intensities of 11Σ+u(v′=1,2,3)→11Σ+g(v″=0) transition at different He or H2 pressure were measured.The ratio of fluorescence intensities versus 1/P(He, H2) can be fitted by a straight line. The slopes yield the cross sections σ(v′=2→v′=1)=(1.4±0.5)×10-16 cm2 and (3.2±1.0)×10-15 cm2; σ(v′=2→v′=3)=(1.2±0.4)×10-16 cm2 and (2.6±0.9)×10-15 cm2 for He and H2, respectively. Cross sections for the effective quenching of the v′=1,2,3 states were also determined. To our knowledge, the cross-sections for these processes are reported for first time.
|
Received: 2009-11-08
Accepted: 2010-02-12
|
|
Corresponding Authors:
SHEN Yi-fan
E-mail: shenyifan01@sina.com; shenyifan01@xju.edu.cn
|
|
[1] Flynn G W,Parmenter C S,Wodtke A M. J. Phys. Chem.,1996,100:12817. [2] Yuan L,Du J,Mullin A S. J. Chem. Phys.,2008,129:014303. [3] Barker J R,Yoder L M,King K D. J. Phys. Chem.,2001,A105:796. [4] Oref I,Tardy D C. Chem. Rev.,1990,90:1407. [5] Chen X L,Chen H M,Li J,et al. Chem. Phys. Letters,2000,318:107. [6] Astill A G,Mclaffery A J,Taylor S C,et al. J. Chem. Phys.,1988,89(1):184. [7] Polly R,Gruder D,Windholz L,et al. Chem. Phys. Letters,1996,249:174. [8] Jarmola A,Tamanis M,Ferber R,et al. J. Quant. Spectro. Rad. Tran.,2005,95:165. [9] Magnier S,Millié Ph. Phys. Rev.,1996,A54(1):204. [10] WANG Qian,LI Peng,DAI Kang,et al(王 倩,李 鹏,戴 康,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2009,29(9):2305. [11] Vadla C,Knezovic S,Morre M. J. Phys.,1992,B25:1337.
|
[1] |
WANG Shu-ying*, YOU De-chang, MA Wen-jia, YANG Ruo-fan, ZHANG Yang-zhi, YU Zi-lei, ZHAO Xiao-fang, SHEN Yi-fan. Experimental Collisional Energy Transfer Distributions for Collisions of CO2 With Highly Vibrationally Excited Na2[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1760-1764. |
[2] |
ZHOU Zi-hao1, YANG Fan2, 3, LI Dong1, WANG Jian-ping2, 3, XU Jian-hua1*. pH Dependent Time-Resolved Fluorescence Spectra of ZnSe Quantum Dots Based on Glutathione Ligands[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3178-3183. |
[3] |
YIN Wen-zhi1,2,3, WANG Ting-yu1,3,ZHU Tuo1, 3, MA Chao-qun1, 3, GU Jiao1, 3, ZHU Chun1, 3, LI Lei1, 3, CHEN Guo-qing1, 3*. The Study on Fluorescence Spectral Characteristics of Three Brands of Milk[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 535-539. |
[4] |
LI Tan-ping, LI Ai-yang. Analysis of Ultra-Trace Metal Impurity Elements in Proprylene Glycol Monomethyl Ether Using Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 618-623. |
[5] |
ZHOU Xue-zhong, LIU Hong-wei*. Accurate Determination of Calcium and Chlorine in Food with Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3567-3571. |
[6] |
LIU Lu-yao1, ZHANG Bing-jian1,2*, YANG Hong3, ZHANG Qiong3. The Analysis of the Colored Paintings from the Yanxi Hall in the Forbidden City[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2054-2063. |
[7] |
SUN Yan-wen1, CHANG Yu2, JIN Yu-fen1, XIE Wen-bing2, CHANG Jing1, YU Ting1*, PAN Li-hua2. Study of Synthesis and Spectral Property of Europium Cryptate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2189-2193. |
[8] |
PENG Heng, LIU Shuai, CHEN Xiang-bai*. Raman Study of Perovskite (C6H5CH2NH3)2PbBr4[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1763-1765. |
[9] |
CHANG Meng-fang1, JIA Meng-hui2, LI Lei1, CHEN Jin-quan1, XU Jian-hua1*. Time-Resolved Fluorescence and Thermodynamic Properties of Staphylococcal Nuclease[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1451-1457. |
[10] |
ZHANG Xiao-he1, 2, MA Chao-qun1, 2*, CHEN Guo-qing1, 2, LIU Huai-bo1, 2, ZHU Chun1, 2, SONG Xin-shu1, 2, ZHU Cong-hai1, 2. The Fluorescnece Lifetime and Quantum Chemistry Calculation of Ethyl Caproate and Ethyl Acetate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 502-505. |
[11] |
GOU Yu-dan1, LU Peng-fei1, HE Jiu-ning1, ZHANG Chang-hua1*, LI Ping1, LI Xiang-yuan2. Measurement of H2O Spectroscopic Parameters near 1.39 μm and Application in Combustion Kinetics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 176-180. |
[12] |
WANG Shu-ying, DAI Kang, SHEN Yi-fan. Full State-Resolved Rotational Distribution of CO2 in Collisions with Highly Vibrationally Excited K2[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3658-3663. |
[13] |
MA Yu-fei1,2, TONG Yao1, ZHANG Li-gong1, HE Ying1, ZHANG Jing-bo1, WANG Long1, LONG Jin-hu1, YU Xin1, SUN Rui2. Study on High Sensitive Detection of Acetylene Trace Gas Based on QEPAS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2869-2872. |
[14] |
CHEN Xiao-lan1, ZHOU Zhen-zhu1, 2*, HAN Zuo-zhen1, LIN Yu-xiang1. The Constraints on the Method of Using Cryogenic Raman Spectroscopy to Determine the Salinities of Fluid Inclusions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(08): 2446-2451. |
[15] |
HUANG Yong-lan1, JIANG Xian-dong1, SHEN Ren-jie1, LI Wu-song2, KANG Ai-hong3. Study of the Adsorption of Hg2+ with Modified PLGA/G5-T Nanofibers[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2036-2040. |
|
|
|
|