Abstract:This paper reports a time-correlated multi-photon counting (TCMPC) technique based on SiPM and its application to time-resolved Raman scattering measurements. Compared with conventional time-correlated single photon counting (TCSPC) technique by using photomultiplier (PMT) or single photon avalanche diode (SPAD) as photon detector, SiPM can distinguish the specific photon-number of the signal pulse, the TCMPC technique based on SiPM eliminates the limitation of the number of photons contained in signal pulse, which must be less than or equal to 1, leading to an increment of the photon counting efficiency by more than 10 times, and greatly reduces the measurement time. In addition, the instrument response function (IRF) of the time-resolved Raman scattering system is enhanced from 81.4 ps for single-photon to 59.7 ps for two-photon detection due to higher time resolution for multi-photon counting than single-photon counting measurement. As a result, it is possible to use a narrower measuring time span to suppress the fluorescence background, a kind of noise that usually occurs in conventional Raman spectroscopy. The TCMPC technique is used to measure the peak-to-background ratio of Raman spectroscopy of CCl4 with different photon numbers of 0.5 p.e. and 1.5 p.e., because the later has a higher photo-electron threshold number that can further reduce the effect of SiPM dark counting and increase the signal-to-noise ratio of Raman spectroscopy, the measured peak-to-background ratio of CCl4 459 cm-1 Raman peak has increased 6.4 times compared with the former. The TCMPC based on Raman scattering measurement technique is compared with the conventional one based on photomultiplier tube (PMT) and lock-in amplifier (LIA). As the timing gate of only several tens of picoseconds is utilized, effective suppression of fluorescence, ambient stray light, dark counting of SiPM and other noise effects have been demonstrated, leading to a better peak-to-background ratio for Raman spectroscopy. The peak-to-background ratios of CCl4 459 cm-1 Raman peak and Si 1st Raman peak, measured by the TCMPC based on Raman spectrometer are 3.9 times and 5.5 times as high as the values obtained by the one based on PMT and LIA, respectively.
Key words:SiPM;TCMPC;TCSPC;Time resolved;Raman scattering;IRF;Ratio of peak to base
苗泉龙,代 雷,李佰成,赵天琦,梁 琨,杨 茹,韩德俊. 基于SiPM和TCMPC的时间分辨拉曼散射测量技术研究[J]. 光谱学与光谱分析, 2018, 38(05): 1444-1450.
MIAO Quan-long, DAI Lei, LI Bai-cheng, ZHAO Tian-qi, LIANG Kun, YANG Ru, HAN De-jun. Time-Resolved Raman Scattering Measurement Based on SiPM and TCMPC Method. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1444-1450.
[1] Renker D, Lorenz E. Journal of Instrumentation, 2009, 4, 04004.
[2] Becker W. Journal of Microscopy, 2006, 222(1): 65.
[3] Morris M D, Matousek P, Towrie M, et al. J. Biomed. Opt., 2005, 10: 14014.
[4] Li B C, Miao Q L, Wang B C, et al. Proc. SPIE, 2016, 9850: 98580L.
[5] Gruber L, Brunner S E, Marton J, et al. Nuclear Instruments & Methods in Physics Research A, 2014, 737: 11.
[6] Max L A. OALib Journal, 2015, 1507: 00863.
[7] Fabio A, Alessandro F, Alberto G, et al. Nuclear Instruments & Methods in Physics Research A, 2015, 784: 34.
[8] Marinov O, Deen J, Tejada J A, et al. Journal of Applied Physics, 2007, 101: 064515.
[9] Gamal A, Paul B, Johann M, et al. Nuclear Instruments & Methods in Physics Research A, 2011, 652: 528.
[10] Gundacker S, Auffray E, Vara N D, et al. Nuclear Instruments & Methods in Physics Research A, 2013, 718: 569.
[11] Sinfield J V, Colic O, Fagerman D, et al. Applied Spectroscopy, 2010, 64: 201.