A Solid Phase Extraction Application of Hybrid Nano B2O3/ZrO2 for Separation and Determination of Trace Indium in Environmental Samples
Ozcan Yalcinkaya1, Harun Ciftci2*, Cigdem Er Caliskan3, Ozge Kalender4, Ali Rehber Turker1
1. Gazi University, Faculty of Science, Department of Chemistry, Ankara, Turkey
2. Ahi Evran University, Faculty of Medicine, Department of Biochemistry, Kirsehir, Turkey
3. Ahi Evran University, Mucur Vocational Training School, Kirsehir, Turkey
4. Ahi Evran University, Faculty of Science and Arts, Department of Chemistry, Kirsehir, Turkey
A Solid Phase Extraction Application of Hybrid Nano B2O3/ZrO2 for Separation and Determination of Trace Indium in Environmental Samples
Ozcan Yalcinkaya1, Harun Ciftci2*, Cigdem Er Caliskan3, Ozge Kalender4, Ali Rehber Turker1
1. Gazi University, Faculty of Science, Department of Chemistry, Ankara, Turkey
2. Ahi Evran University, Faculty of Medicine, Department of Biochemistry, Kirsehir, Turkey
3. Ahi Evran University, Mucur Vocational Training School, Kirsehir, Turkey
4. Ahi Evran University, Faculty of Science and Arts, Department of Chemistry, Kirsehir, Turkey
摘要： Hybrid nanomaterials have attracted considerable interest in environmental science, analytical chemistry and atomic spectroscopy. In the present study, a column solid phase extractioo procedure was developed for the separation and preconcentration of indium in various matrixes by using hybrid nanomaterial B2O3/ZrO2 (HNMBZ). Various experimental and analytical parameters such as sample solution pH, sample solution volume, flow rate of sample solution and eluent, volume and concentration of eluent aod amount of HNMBZ, effect of common matrix ions and capacity of sorbent were investigated. The adsorbed metal ions on HNMBZ were eluted with 6 mL of 1 mol·L-1 HNO3 solutions and their concentrations were determined by high-resolution continuum source flame atomic absorption spectrometry (HR-CS FAAS). Under the optimized conditions, detection limits for indium for 3 pixels and 5 pixels were found as 0.20 and 0.16 μg·L-1, respectively. The accuracy of the procedure was checked by spiked water samples. The developed procedure was successfully applied to real samples for the separation and determination of indium.
Abstract：Hybrid nanomaterials have attracted considerable interest in environmental science, analytical chemistry and atomic spectroscopy. In the present study, a column solid phase extractioo procedure was developed for the separation and preconcentration of indium in various matrixes by using hybrid nanomaterial B2O3/ZrO2 (HNMBZ). Various experimental and analytical parameters such as sample solution pH, sample solution volume, flow rate of sample solution and eluent, volume and concentration of eluent aod amount of HNMBZ, effect of common matrix ions and capacity of sorbent were investigated. The adsorbed metal ions on HNMBZ were eluted with 6 mL of 1 mol·L-1 HNO3 solutions and their concentrations were determined by high-resolution continuum source flame atomic absorption spectrometry (HR-CS FAAS). Under the optimized conditions, detection limits for indium for 3 pixels and 5 pixels were found as 0.20 and 0.16 μg·L-1, respectively. The accuracy of the procedure was checked by spiked water samples. The developed procedure was successfully applied to real samples for the separation and determination of indium.
基金资助: the Scientific and Technological Research Council of Turkey (TUBITAK Grants no. 110T111，214Z221)
通讯作者:
Harun Ciftci
E-mail: harunciftci@yahoo.com
作者简介: Harun Ciftci, Ahi Evran University, Faculty of Medicine, Department of Biochemistry, Kirsehir-Turkey
引用本文:
Ozcan Yalcinkaya, Harun Ciftci, Cigdem Er Caliskan, Ozge Kalender, Ali Rehber Turker. A Solid Phase Extraction Application of Hybrid Nano B2O3/ZrO2 for Separation and Determination of Trace Indium in Environmental Samples[J]. 光谱学与光谱分析, 2018, 38(04): 1283-1289.
Ozcan Yalcinkaya, Harun Ciftci, Cigdem Er Caliskan, Ozge Kalender, Ali Rehber Turker. A Solid Phase Extraction Application of Hybrid Nano B2O3/ZrO2 for Separation and Determination of Trace Indium in Environmental Samples. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1283-1289.
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