Abstract:In this paper, silver nanocubes were prepared by seed growth method. The prepared sliver nanocubes showed a uniform size distribution, with a RSD of 7.2%, according to scanning electron microscopy (SEM) characterization. CTAC on the surface of silver nanocubes were replaced by citrate. Based on SLIPS substrate with super lubrication properties, three dimensional SERS substrate was constructed with sliver nanocubes as building block. The three dimensional SERS substrate was used to detect tricyclazole and thiram in water and ethanol. The limit of detection for detecting tricyclazole and thiram could reach 52.8 and 41.6 nmol·L-1, respectively. The experiment results show that the three dimensional SERS substrate has an excellent detection sensitivity. Therefore, the three dimensional SERS substrate has great significance for detecting pesticide in real-world environment.
杨焕娣,林 翔,刘远兰,赵海燕,王 利. 银纳米立方三维SERS基底制备及用于多种溶剂中农药的快速检测[J]. 光谱学与光谱分析, 2018, 38(01): 99-103.
YANG Huan-di, LIN Xiang, LIU Yuan-lan, ZHAO Hai-yan, WANG Li. Preparation of Three-Dimensional Hotpot SERS Substrate with Sliver Nanocubes and Its Application in Detection of Pesticide. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 99-103.
[1] LIU An-qi,LI Gong-ke,HU Yu-ling(刘安琪, 李攻科, 胡玉玲). Journal of Food Safety & Quality(食品安全质量检测学报),2015,6(6): 2214.
[2] FAN Yu-xia,LAI Ke-qiang,HUANG Yi-qun(樊玉霞, 赖克强, 黄轶群). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2014,34(7): 31.
[3] Chen S, Meng L Y, Shan H Y, et al. ACS Nano, 2015, 10(1): 581.
[4] Xu J, Du J, Jing C, et al. ACS Applied Materials & Interfaces, 2014, 6(9): 6891.
[5] Hara R, Fukuoka T, Takahashi R, et al. RSC Advances, 2015, 5(2): 1378.
[6] Li X, Lee H K, Phang I Y, et al. Analytical Chemistry, 2014, 86(20): 10437.
[7] Liu H, Yang Z, Meng L, et al. Journal of the American Chemical Society, 2014, 136(14): 5332.
[8] Yang Q, Deng M, Li H, et al. Nanoscale, 2015, 7(2): 421.
[9] Li P, Li Y, Zhou Z K, et al. Advanced Materials, 2016, 28(13): 2511.
[10] Wong T S, Kang S H, Tang S K Y, et al. Nature, 2011, 477(7365): 443.
[11] Yang S, Dai X, Stogin B B, et al. Proceedings of the National Academy of Sciences, 2016, 113(2): 268.
[12] Liu H, Yang L, Liu J. TrAC Trends in Analytical Chemistry, 2016, 80: 364.
[13] Ma Y, Li W, Cho E C, et al. ACS Nano, 2010, 4(11): 6725.
[14] Mehtala J G, Zemlyanov D Y, Max J P, et al. Langmuir, 2014, 30(46): 13727.
[15] Tang H, Fang D, Li Q, et al. Journal of Food Science, 2012, 77(5): T105.
[16] Tang H R, Li Q Q, Ren Y L, et al. Chinese Chemical Letters, 2011, 22(12): 1477.
[17] Shen W, Lin X, Jiang C, et al. Angewandte Chemie International Edition, 2015, 54(25): 7308.
[18] Liu B, Han G, Zhang Z, et al. Analytical Chemistry, 2011, 84(1): 255.
[19] Zhu Y, Li M, Yu D, et al. Talanta, 2014, 128: 117.
[20] CHEN Yang, LI Gong-ke, HU Yu-ling(陈 漾,李攻科,胡玉玲). Journal of Analytical Science(分析科学学报),2015,31(3): 307.