Research on Visible-Near Infrared Spectral Characterization of Purplish Soil Contaminated with Petroleum Hydrocarbon and Estimation of Pollutant Content
YIN Wen-qi1, CHEN Zhi-li1*, JIAO Yu-wei2, LIU Hong-tao3, LIU Qiang3
1. Department of National Defense Architecture Planning and Environmental Engineering, Logistical Engineering University，Chongqing 401311, China
2. Institute of Remote Sensing and Earth Sciences, Hangzhou Normal University, Hangzhou 311100, China
3. Department of Military Oil Application and Management Engineering, Logistical Engineering University，Chongqing 401311, China
Abstract：Hyperspectral remote sensing technology is an effective method to monitor petroleum contamination. It is mainly used in offshore oil spill, while few study has been focusing on soil petroleum-hydrocarbon contamination. In this case, due to the shortage of research on soil petroleum-hydrocarbon contamination, three kinds of petroleum hydrocarbons are selected, including diesel, gasoline and motor oil, to characterize the absorption features of petroleum hydrocarbons in spectra yielded from contaminated purplish soils in condition of different types and different concentrations of petroleum hydrocarbons and extract the spectral absorption characteristic band of soil contaminated by petroleum hydrocarbon. Based on this, seven kinds of spectral transformations and correlation analysis were conducted to select the most sensitive spectral variables with petroleum hydrocarbon content. The estimation model was established via univariate regression and multiple stepwise linear regression (SMLR) respectively and verified ultimately. The results show that the spectral signatures of soil contaminated by diesel, motor oil and gasoline are in the vicinity of 1 200, 1 700 and 2 300 nm, and the absorption depth is shown as follows: motor oil>gasoline>diesel. Multiple stepwise linear regression method is superior to univariate regression method. The coefficients of determination (R2) of diesel, motor oil and gasoline are greater than 0.95. Moreover, the root mean square error of calibration (RMSEC) is less than 0.47 and the root mean square error of validation (RMSEC) is less than 0.56, which demonstrates higher estimation accuracy.
基金资助: National Science Foundation of China (21377166)
通讯作者:
陈志莉
E-mail: 1012262034@qq.com
作者简介: YIN Wen-qi, (1992—), a Master of Department of National Defense Architecture Planning and Environmental Engineering, Logistical Engineering University e-mail:
645358932@qq.com
引用本文:
尹文琦，陈志莉，焦雨薇，刘洪涛，刘 强. 石油烃污染紫色土的可见-近红外光谱特征及其含量估算研究[J]. 光谱学与光谱分析, 2017, 37(12): 3924-3931.
YIN Wen-qi, CHEN Zhi-li, JIAO Yu-wei, LIU Hong-tao, LIU Qiang. Research on Visible-Near Infrared Spectral Characterization of Purplish Soil Contaminated with Petroleum Hydrocarbon and Estimation of Pollutant Content. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3924-3931.
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