Study on the Three-Dimensional Fluorescence Spectra of Oil Mixture and Its Composition Based on Tri-PLS Model
WANG Yu-tian1, ZHANG Li-juan1, 2*, ZHAO Xu1, CHEN Yi-qiang3, PAN Zhao1, CAO Li-fang1, XU Jing1, YUAN Yuan-yuan1, NIU Kai-zeng1, ZHANG Ya-ji1
1. Key Lab of Measurement Technology and Instrumentation of Hebei Province, Yanshan University，Qinhuangdao 066004, China
2. Hebei University of Environmental Engineering, Qinhuangdao 066102, China
3. Shenyang Academy of Instrumentation Science Co., Ltd., Shenyang 110043, China
Abstract：A new method which extend the partial least squares (PLS) method to three-dimensional (tri-PLS) and don’t need to care about the eigenvalue is presented to determinate the content of a variety of mineral oil mixture with overlapping spectra. This method is used to study the three-dimensional fluorescence spectra of the mixture of diesel, gasoline and kerosene. The 3D data matrix is constructed on the basis of the sample sequence, the excitation wavelength and the emission wavelength. The combination of 3D data matrix and the concentration matrix can be modeled by tri-PLS to predict the test samples.The experimental results show that the modeling precision of tri-PLS is superior to PARAFAC.
王玉田，张立娟，赵 煦，陈毅强，潘 钊，曹丽芳，徐 婧，苑媛媛，牛凯增，张亚吉. 基于tri-PLS模型的油类混合物三维荧光光谱及其成分的研究[J]. 光谱学与光谱分析, 2017, 37(12): 3771-3775.
WANG Yu-tian, ZHANG Li-juan, ZHAO Xu, CHEN Yi-qiang, PAN Zhao, CAO Li-fang, XU Jing, YUAN Yuan-yuan, NIU Kai-zeng, ZHANG Ya-ji. Study on the Three-Dimensional Fluorescence Spectra of Oil Mixture and Its Composition Based on Tri-PLS Model. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3771-3775.
[1] TANG Yuan-he, LIU Qing-song, MENG Lei, et al(唐远河, 刘青松, 蒙 磊, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2015, 35(2): 424.
[2] Chelsea Spier, William T Stringfellow, Terry C Hazenl. Environmental Pollution, 2013，173: 225.
[3] Bernabeu A M, Fernandez-Fernadez S, Bouchette F. Journal of Hazardous Materials, 2013, 250~251: 84.
[4] WU Zhong-biao(吴中标). Air Pollution Monitoring and Supervision(大气污染监测与监督). Beijing: Chemical Industry Press(北京：化学工业出版社)，2003. 18.
[5] SHANG Li-ping, YANG Ren-jie(尚丽平, 杨仁杰). Field Fluorescence Spectrum Technology and Application(现场荧光光谱技术及其应用). Beijing: Science Press(北京: 科学出版社), 2009.
[6] Bro R. Journal of Chemometrics, 1996, 10: 47.
[7] Goicoechea H C, Calimag-Williams K, Campiglia A D. Analytica Chimica Acta, 2012, 717(5): 100.
[8] Calimag-Williams K, Knobel G, Goicoechea H C, et al. Analytica Chimica Acta, 2014, 811: 60.
[9] Singh K P, Malik A, Basant N, et al. Analytica Chimica Acta, 2007, 584(2): 385.
[10] Yang R, Liu R, Xu K. Food Bioscience, 2013, 2: 61.
[11] Shahlaei M, Fassihi A, Saghaie L, et al. Research in Pharmaceutical Sciences, 2014, 9(2).
[12] Hanafi M, Ouertani S S, Boccard J, et al. Computational Statistics & Data Analysis, 2015, 83: 129.
[13] PAN Zhao(潘 钊). The study of Oil Pollution Recognition Measurement Method and Experiment Based on Fluorescence Spectrum Analysis(基于荧光光谱分析的石油类污染物识别测量方法及其实验研究). Yanshan University(燕山大学), 2012.
