Analysis of Hydrogen Bond Structure in Ice Ih Surface of Film with Raman Spectra
LI Fa-bing1, LI Zhan-long1, MEN Zhi-wei1, LI Ye-qiu1*, OUYANG Shun-li2*
1. Coherent Light and Atomic and Molecular Spectroscopy Laboratory, College Physics，Jilin University, Changchun 130012, China
2. Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science & Technology, Baotou 014010, China
Abstract：Water is one of the most important and basic materials in living systems which has been extensively studied because of its peculiar properties and abnormal properties. Raman spectral study on the water molecular structure is highly desirable. It obtains the information of molecular vibration and rotation to understand the structure and the interaction of water molecules. The Raman spectra of ice Ih surface of film is obtained in the temperature range of -20 to -190 ℃ at atmospheric pressure. The spectra show that O∶H van der Waals bond and O—H polar-covalent bond shift to higher and lower wave number, respectively. The relationship between Raman shift and temperature is linear, by comparing the slope of different vibration modes to determine the relationship between the expansion and contraction of the bond length, which reveal that the ice Ih density increases with cooling. The results indicate that it is important for hydrogen bond in the process of cooling. Meanwhile, Raman intensity of O—H bond vibration mode and O∶H bond vibration mode occur a mutation at -150 ℃, this results showed that the phase transition of ice Ih-ice Ⅺ (i. e. proton-ordered phase of ice Ih).
李发兵，李占龙，门志伟，李业秋，欧阳顺利. 利用拉曼光谱分析冰Ih相的表面薄层的氢键结构[J]. 光谱学与光谱分析, 2017, 37(06): 1683-1686.
LI Fa-bing, LI Zhan-long, MEN Zhi-wei, LI Ye-qiu, OUYANG Shun-li. Analysis of Hydrogen Bond Structure in Ice Ih Surface of Film with Raman Spectra. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1683-1686.
[1] MENG Sheng, WANG En-ge(孟 胜，王恩哥). Basic Science Theory and Experiment of Water(水基础科学理论与实验). Beijing: Higher Education Press(北京: 北京大学出版社)，2014. 80.
[2] Petkov V, Ren Y, Suchome l M. Journal of Physics: Condensed Matter，2012, 24(15): 155102.
[3] Sun C Q, Zhang X, Zheng W. Chemical Science, 2012, 3(5): 1455.
[4] Sun C Q, Zhang X, Zhou J, et al. The Journal of Physical Chemistry Letters, 2013, 4(15): 25650
[5] Medcraft C, McNaughton D, Thompson C D, et al. Astrophys, 2012, 758：17.
[6] OUYANG Shun-li, WU Nan-nan(欧阳顺利, 吴楠楠). Chinese Journal of Low Temperature Physics(低温物理学报), 2013, 1：8.
[7] JIA Li-hua, WANG Yi-ding, MEN Zhi-wei, et al(贾丽华，王一丁，门志伟，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2012, 32(5): 1259.
[8] Li T, Li F, Li Z, et al. Optics Letters, 2016, 41(6): 1297.
[9] Otto K E, Xue Z, Zielke P, et al. Physical Chemistry Chemical Physics, 2014, 16(21): 9849.
[10] Men Z, Fang W, Wang S, et al. Journal of Raman Spectroscopy, 2015, 46(4): 388.
[11] LI Zhan-long, WANG Yi-ding, ZHOU Mi, et al(李占龙, 王一丁, 周 密, 等). Acta Phys. Sin.(物理学报)，2012, 61：064217.
[12] Sun C Q, Zhang X, Fu X, et al. The Journal of Physical Chemistry Letters, 2013, 4(19): 3238.
[13] Shigenari T, Abe K. The Journal of Chemical Physics, 2012, 136(17): 174504.
