Abstract:Chromophoric dissolved organic matter (CDOM) represents the fraction of the dissolved organic pool which absorbs light in the visible as well as UV ranges. It could affect the color of the waters. It is necessary to study it during in research on ecosystem, remote sensing of the water color and the cycle of carbon in waters. CDOM can fluoresce when excited, so fluorescence spectrum has been used to study its origin, distribution, and change.In the present article the fluorescence spectrophotometer was used to study the relation between the fluorescence intensity, spectrum area and the concentration of CDOM. When the concentration of CDOM is low(less than 75 mg·L-1), there is a better linear relationship(r2>0.98)between the fluorescence intensity, the spectrum area and the concentration of CDOM. Meanwhile good linear relations were found between the fluorescence intensity and spectrum area, which showed the same changeable trend of the fluorescence intensity and spectrum area with the concentration change of CDOM. A method was established to quantify the concentration of CDOM in water from different source using the linear relationship between the spectrum area and the concentration. It suits the complicated constituent analysis of CDOM and could really and accurately show the concentration of CDOM in natural water.
Key words:CDOM;Quantitative analysis;Emission spectrum;Spectrum area
柳先平,李磊*,戴金凤,王小如,黎先春 . 不同水体中有色可溶性有机物质荧光光谱定量分析研究[J]. 光谱学与光谱分析, 2007, 27(10): 2083-2087.
LIU Xian-ping, LI Lei*, DAI Jin-feng, WANG Xiao-ru, Frank Lee S C. Determination of Chromphoric Dissolved Organic Matter in Water from Different Sources. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(10): 2083-2087.
[1] Tiit Kutser, Pierson Donald C, Kari Y Kallio, et al. Remote Sensing of Environment, 2005, 94: 535. [2] CHEN Chu-qun, PAN Zhi-lin, SHI Ping(陈楚群,潘志林,施 平). Journal of Tropical Oceanography(热带海洋学报),2003,22(5):33. [3] Chen Robert F, Paul Bissett, Paula Coble, et al. Marine Chemistry, 2004, 89: 257. [4] Bricaud A, Morel A, Prieur L. Limnology and Oceanography, 1981, 26: 43. [5] WU Yong-sen, ZHANG Shi-kui, ZHANG Xu-qin, et al(吴永森,张士魁,张绪琴,等). Oceanologia et Limnologia Sinica(海洋与湖沼), 2002, 33(4): 402. [6] Warnock Roderick E, Gieskes Winfried W C, van Laar Sandor. Journal of Sea Research,1999,42: 169. [7] Shank G C, Zepp Richard G, Whitehead Robert F, et al. Estuarine, Coastal and Shelf Science, 2005, 65: 289. [8] Piotr Kowalczuk, Joanna Ston-Egtiert, Cooper William J, et al. Marine Chemistry, 2005, 96: 273. [9] Hiroaki Sasaki H, Miyamura T, Saitoh S, et al. Estuarine, Coastal and Shelf Science, 2005, 64: 447. [10] XIA Da-ying, LI Bao-hua, WU Yong-sen, et al(夏达英,李宝华,吴永森,等). Oceanologia et Limnologia Sinica(海洋与湖沼), 1999, 30(6): 719. [11] Keith D J, Yoder J A, Freeman S A. Estuarine, Coastal and Shelf Science, 2002, 55: 705. [12] Stedmon Colin A, Markager Stiig, Bro Rasmus. Marine Chemistry, 2003, 82: 239. [13] Vignudelli S, Santinelli C, Murru E, et al. Estuarine, Coastal and Shelf Science, 2004, 60: 133. [14] Boyd Thomas J, Osburn Christopher L. Marine Chemistry, 2004, 89: 189. [15] Jennifer Boehme, Paula Coble, Robyn Conmy, et al. Marine Chemistry, 2004, 89: 3. [16] ZHAO Nan-jing, LIU Wen-qing, LIU Jian-guo, et al(赵南京,刘文清,刘建国,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005,25(7):1077. [17] Yang Y H, Zhang D H. Soil Sci. Plant Analysis, 1995, 26: 2333. [18] WU Yong-sen, ZHANG Xu-qin, ZHANG Shi-kui, et al(吴永森,张绪琴,张士魁,等). Acta Oceanologica Sinica(海洋学报),2004,26(4):58.