Gas Concentration Measurement Based on the Integral Value of Absorptance Spectrum
LIU Hui-jun1,2, TAO Shao-hua1,2*, YANG Bing-chu1, DENG Hong-gui1
1. School of Physics and Electronics, Central South University, Changsha 410083, China 2. Institute of Super Microstructure and Ultrafast Process in Advanced Materials, School of Physics & Electronics, Central South University, Changsha 410083, China
Abstract：The absorptance spectrum of a gas is the basis for the qualitative and quantitative analysis of the gas by the law of the Lambert-Beer. The integral value of the absorptance spectrum is an important parameter to describe the characteristics of the gas absorption. Based on the measured absorptance spectrum of a gas, we collected the required data from the database of HITRAN, and chose one of the spectral lines and calculated the integral value of the absorptance spectrum in the frequency domain, and then substituted the integral value into Lambert-Beer’s law to obtain the concentration of the detected gas. By calculating the integral value of the absorptance spectrum we can avoid the more complicated calculation of the spectral line function and a series of standard gases for calibration, so the gas concentration measurement will be simpler and faster. We studied the changing trends of the integral values of the absorptance spectrums versus temperature. Since temperature variation would cause the corresponding variation in pressure, we studied the changing trends of the integral values of the absorptance spectrums versus both the pressure not changed with temperature and changed with the temperature variation. Based on the two cases, we found that the integral values of the absorptance spectrums both would firstly increase, then decrease, and finally stabilize with temperature increasing, but the ranges of specific changing trend were different in the two cases. In the experiments, we found that the relative errors of the integrated values of the absorptance spectrum were much higher than 1% and still increased with temperature when we only considered the change of temperature and completely ignored the pressure affected by the temperature variation, and the relative errors of the integrated values of the absorptance spectrum were almost constant at about only 1% when we considered that the pressure were affected by the temperature variation. As the integral value of the absorptance spectrum varied with temperature and the calculating error for the integral value fluctuates with ranges of temperature, in the gas measurement when we used integral values of the absorptance spectrum，we should select a suitable temperature range，that is，a more stable absorption range to reduce error caused by the temperature variation and obtain a more accurate measurement result.
刘慧军1, 2，陶少华1, 2*，杨兵初1，邓宏贵1 . 基于光谱吸收率积分的气体浓度测量方法 [J]. 光谱学与光谱分析, 2015, 35(12): 3490-3494.
LIU Hui-jun1,2, TAO Shao-hua1,2*, YANG Bing-chu1, DENG Hong-gui1 . Gas Concentration Measurement Based on the Integral Value of Absorptance Spectrum. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(12): 3490-3494.
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