Photoluminescence of Sinthetic Scapolite Na4Ca4Al6Si9O24 Phosphors Activated with Ce3+ and Tb3+ and Energy Transfer from Ce3+ to Tb3+
MA Yuan-yuan, HE Jiu-yang, Aziguli·Reheman, Bahadeer·Rouzi, Aierken·Sidike*
College of Physics and Electronic Engineering of Xinjiang Normal University,Key Laboratory of Mineral Luminescent Material and Microstructure of Xinjiang,Urumqi 830054,China
Abstract:Natural scapolite including the S-2 impurity is a typical silicate luminescent mineral. According to the formation conditions and chemical composition of natural scapolite, we synthesized Na4Ca4Al6Si9O24(scapolite) by the high temperature solid-phase reaction, and prepared the synthetic scapolite phosphors activated with Ce3+ and Tb3+. The photoluminescence (PL) properties of the obtained phosphors were studied. The results indicated that the PL intensity of green (545 nm) emission corresponding to the 5D4 →7F5 transition within Tb3+in the Ce3+, Tb3+-codoped samples was much higher than that of the Tb3+-doped samples. The PL properties of the samples activated with various Ce3+ concentrations were measured, and their fluorescence lifetime and energy transfer mechanism were analyzed. We proved that there was energy transfer from Ce3+ to Tb3+, and the energy transfer efficiency was at its maximum when the Ce3+ to Tb3+ mass ratio was 0.02∶0.03. Upon measurement by chromaticity coordinates, we found that the luminescence of the samples could be adjusted in the green area with varying Ce3+ concentrations. We thus deem that scapolite phosphors Na4Ca4Al6Si9O24∶Ce3+, Tb3+ are promising to become the new white LED phosphors.
马媛媛,何久洋,阿孜古丽·热合曼,巴哈德尔·肉孜,艾尔肯·斯地克* . Na4Ca4Al6Si9O24∶Ce3+, Tb3+荧光粉合成及其能量传递研究 [J]. 光谱学与光谱分析, 2015, 35(11): 3241-3246.
MA Yuan-yuan, HE Jiu-yang, Aziguli·Reheman, Bahadeer·Rouzi, Aierken·Sidike* . Photoluminescence of Sinthetic Scapolite Na4Ca4Al6Si9O24 Phosphors Activated with Ce3+ and Tb3+ and Energy Transfer from Ce3+ to Tb3+. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(11): 3241-3246.
[1] Pan Zhengwei, He Hong, Song Xiufeng, et al. Journal of the Chinese Ceramic Society, 2009, 37, 1590. [2] Zeng Qihua, Zhang Xinguo, Liang Hongbin, et al. Journal of the Chinese Society of Rare Earth, 2011, 29, 8. [3] Aierken Sidike, Kusachi I, Kobayashi S, et al. Physics and Chemistry of Minerals, 2008, 35, 137. [4] Alitunguli Maimaitinaisier, Muyasier Kaiheriman, Aierken Sidike. Chinese Journal of Luminescence, 2013, 34, 1596. [5] Muyasier Kaiheriman, Alitunguli Maimaitinaisier, Aziguli Rehiman, et al. Phys. Chem. Minerals, 2014, 41: 227. [6] Wang Y H, Wang Z Y, Zhang P Y, et al. Materials Letters, 2004, 58, 3308. [7] Jiao Haiyan, Wang Yuhua. Applied Physies B: laster and Optics, 2010, 98:423. [8] Jiao Haiyan, Wang Yuhua. Journal of the Electrochemieal Soeiety, 2009, 156(5): 117. [9] Jiao Haiyan, Wang Yuhua, Zhang Jiachi. Journal of Inorganic Materials, 2008, 23(3): 471. [10] Song Enhai, Zhao Weiren, Dou Xihua, et al. Journal of the Chinese Society of Rare Earth, 2012, 30(1): 41. [11] He Jiuyang, Taximaiti·Yusupu, Ajimu·Abulai, et al. Chinese Journal of Luminescence, 2010, 31: 176. [12] Cao Jinquan, Wang Shubin, Tie Shaolong. Chinese Journal of Luminescence, 2000, 21:288. [13] Luo Hongde, Liu Jie, Zheng Xiao, et al. Journal of Materials Chemistry, 2012, 22:15887. [14] Jiang Tingming, Yu Xue, Xu Xuhui, et al. Chin. Phys. B, 2014, 23(2):028505. [15] Zhang Siyuan. Spectroscopy of Rare Earth Ions. Beijing: Science Press, 2001. 139.