摘要: A new piperazinium 4-nitro phenolate monohydrate single crystal (PNP) was grown by employing the solution growth technique piperazine and 4-nitrophenol, were the source material used for the growth, acetonitrile is used as solvent. The grown crystal was characterized by Single X-ray analysis and it shows that piperazinium 4-nitrophenol monohydrate crystallizes in the monoclinic space group P2 1/c, with cell parameters a=10.902 5(4) Å, b=6.226 1(3) Å, c=14.031 8(5) Å, and z=4. The lattice parameters of the substances were also determined by using powder diffraction methods. The functional groups are identified by using FTIR spectral analysis. The absorbance of title compound were analyzed using UV-Vis spectra. The thermo analytical properties of the crystal were studied using TG, DTA.
Abstract:A new piperazinium 4-nitro phenolate monohydrate single crystal (PNP) was grown by employing the solution growth technique piperazine and 4-nitrophenol, were the source material used for the growth, acetonitrile is used as solvent. The grown crystal was characterized by Single X-ray analysis and it shows that piperazinium 4-nitrophenol monohydrate crystallizes in the monoclinic space group P2 1/c, with cell parameters a=10.902 5(4) Å, b=6.226 1(3) Å, c=14.031 8(5) Å, and z=4. The lattice parameters of the substances were also determined by using powder diffraction methods. The functional groups are identified by using FTIR spectral analysis. The absorbance of title compound were analyzed using UV-Vis spectra. The thermo analytical properties of the crystal were studied using TG, DTA.
N. Swarnasowmya, S. Sampath Krishnan . Synthesis, Growth and Spectroscopic Studies of Piperazinium Paranitrophenolate Monohydrate Crystals[J]. 光谱学与光谱分析, 2015, 35(10): 2958-2962.
N. Swarnasowmya, S. Sampath Krishnan . Synthesis, Growth and Spectroscopic Studies of Piperazinium Paranitrophenolate Monohydrate Crystals. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(10): 2958-2962.
[1] Dmitriev V G, Gurzadyan G G, Nicogosyan D N. Handbook of Nonlinear Optical Crystals. New York: Springer Verlag,1999. [2] Wong M S, Bosshard C, Pan F, et al. Adv. Mater., 1996, 8: 677. [3] Zyss J, Nicoud J F, Coquillay M. J. Chem. Phys., 1984, 81: 4160. [4] Ledoux I, Badan J, Zyss J, et al. J. Opt. Soc. Am., 1987. [5] Bhat M N, Dharmaprakas S M. J. Cryst. Growth, 2002, 236: 379; Nicoud J F, Twieg R J, Chemla D S, et al. Nonlinear Optical Properties of Organic Molecules and Crystals. London: Academic Press,1987. [6] Dhanuskodi S, Vasantha K. Cryst. Res. Technol., 2004, 39: 259. [7] Martin Brito Dhas SA, Natarajan S. Cryst. Res. Technol., 2007, 42: 471. [8] Ramachandra Raja C, Gokila G, Antony Joseph A. Spectrachim Acta A,2009,72: 753. [9] Belostotskii A M, Gottlieb H E, Adep P, et al. Chem. Eur. J.,1999,5:449. [10] Freeman F, Tsegai Z M, Kasner M L, et al. J. Chem. Educ.,2000,77:661. [11] Topsom R D. Prog. Phys. Org. Chem., 1976, 12. [12] Kaloustian M K, Denis N, Mager S, et al. J. Am. Chem. Soc.,1976,98:956. [13] Dega-Szafran Z, Jaslolski M, Kurzyca I, et al. J. Mol. Struct.,2002,614:23. [14] Brahadeeswaran S, Venkataramanan V, Sherwood J N, et al. J. Mater. Chem.,1998,8:613. [15] Brahadeeswaran S, Venkataramanan V, Bhat H L. J. Cryst. Growth, 1999,205:548. [16] Boaz B Milton, Linet J Mary, Varghese Babu, et al. J. Cryst. Growth, 2005,280:448. [17] Harrpwfield J M, Skelton B W, White A H. Aust. J. Chem., 1995, 48: 1333. [18] Harrowfield J M, Sharma R P, Skeleton B W, et al. Aust. J. Chem.,1998,8(3):775. [19] Varsanyi G. Assignments for Vibrational Spectra of Seven Hundred Benzene Derivativesw, Vol. 1-2, Adam Hilger, 1974. [20] Evans J C. Spectrochima. Acta A,1960,16:1382. [21] Bist H D, Brand J C D, Williams D R. J. Mol. Spectrosc., 1967, 24: 402. [22] Sethuraman K, Ramesh Babu R, Vijayan N, et al. Spectrochimi. Acta A,2007,66:707. [23] Altomare A, Cascarno G, Guagliardi A, et al. J. Appl. Crystollagr.,1999,32:115. [24] Havlicek D, Chudoba V, Nemec I, et al. J. Mol. Struct.,2002,606:101. [25] Milton Boaz B, Jerome Das S. J. Cryst. Growth, 2005, 279:383. [26] Vesta C, Uthrakumar R, Jerome Das S, et al. Sect. E. Struct. Rep.,2008,64:m451(Online). [27] Vesta C, Uthrakumar R, Jerome Das S, et al. J. Mater. Sci. Technol.,2007,23:855. [28] Jonie Varjula A, Vesta C, Justin Raj C, et al. Mater. Lett.,2007,61:5053. [29] Vijayan N, Ramesh Babu R, Gunsekaran M, et al. [30] Jin Z, Qin B, Lin J, et al. Spectrochim. Acta, 2005,61(A):665. [31] Gan L H, Roshan Deen G, Gan Y Y, et al. J. Colloid Inter. Sci., 1996,183:329. [32] Gowri S, Uma Devi T, Sajan D, et al. Spectrochim. Acta,2011,81(A):257. [33] Dega-Szafran Z, Katrusiak A, Szafran M. J. Mol. Struct., 2008, 875:577. [34] Kolodziejski W, Mazurek A P, Guttman T K. Chem. Phy. Lett.,2000,328:263. [35] Willard H H, Merritt Jr L L, Dean J A, et al. Instrumental Methods and Analysis, Sixth ed., Wadsworth Publishing Company, USA, 1986. 609. [36] Wojciechowski A, Ozga K, Reshak A H, et al. Mater. Lett.,2010,64:1957. [37] Kityk V, Marciniak B, Melfleh A. J. Phys. D: Appl. Phys., 2001, 34: 1. [38] Silverstein R M, Clayton Basseler G, Morrill T C. Spectrometric Identification of Organic Compounds, Fifth ed., John Wiley & Sons, Inc., New York, 1998. [39] Van Hundelshausen V. Phys. Lett. A, 1971, 34: 405. [40] Rao K V, Smakula A. J. Appl. Phys., 1966, 37: 319. [41] Balarew C, Duhlew R. J. Solid State Chem., 1984, 55: 1. [42] Sheik-Bahae M, Ali A Said, Tai-Huie Wei, et al. IEEE J. Quant. Elect.,1990,26(4):760. [43] Kanagasekaran T, Mythili P, Srinivasan P, et al. J. Cryst. Growth Des.,2008,8:2335. [44] Shettigar S, Umesh G, Chandrasekaran K, et al. Syn. Met., 2007, 157: 142. [45] Yun Shan Zhou, En Bo Wang, Jung Peng. Poly., 1999, 18: 1419.