Feieling Skarn-Type Pb-Zn Deposit in Southwest Margin of Yunkai Massif
ZENG Chang-yu1, 4, ZHAO Ming-zhen2, LI Hong-zhong3, 4*, NIU Jia1, 4, ZHANG Jie-tang1, 4, HE Jun-guo1, 4*, ZHOU Yong-zhang1, 4, YANG Zhi-jun1, 4
1. School of Earth Science and Geological Engineering, Sun Yat-sen University, Guangzhou 510641, China 2. School of Material Science and Engineering, South China University of Technology, Guangzhou 510275, China 3. Key Laboratory of Mineral Resource, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China 4. Guangdong Provincial Key Lab of Geological Proceses and Mineral Resource Survey, Guangzhou 510275, China
Abstract:The Feieling Pb-Zn deposit of skarn-type is located the in Southwest margin of Yunkai massif, China. This ore deposit can be divided into wall rock near ore, concealed rock mass, endoskarn, exoskarn and orebody. The Raman and FTIR spectrum are conducted to study the mineralogical characteristics of quartz and calcite from five types of rocks from Feieling skarn-type deposit. The analysis shows that the quartz included in the near ore wall rock, endoskarn and exoskarn, comparing with recrystallized quartz of concealed rock mass, has a tend to change into low symmetry quartz in varying degrees. The crystalinity and order degree of quartz from near ore wall rock to concealed rock mass and to endoskarn are becoming higher, but that of quartz from different exoskarn samples display no regular. The origin or the quartz microstructure changes may be related to the multi-stage evolution of skarn mineralization process. The quartz, included in near ore wall rock, endoskarn and exoskarn, become easier to recrystallize and adjust microstructure under the influence of the multi-stage hydrothermal and temperature effect. In anyone sample, the earlier crystalline calcite, showing subhedral-euhedral crystal, display higher crystalinity and order degree. On the contrary, the later crystalline calcite, showing xenomorphic crystal, display lower crystalinity and order degree. Calcite crystal of exoskarn rock contains some silica impurity, while endoskarn and orebody rock is pure. The purity of calcite crystal may relate to Multi-stage evolution of skarn mineralization process. At the early and late skarn stage, active silica-containing fluid is easier to join into calcite, which is under higher temperature environments. On the contrary, at the late quartz-surfide stage, the later crystalized calcite displays higher purity, which is under lower temperature environments. Therefore, spectral characteristics of quartz and calcite reflect multi-stage evolution of skarn mineralization process.
[1] ZHOU Yong-zhang, ZENG Chang-yu, LI Hong-zhong, et al(周永章, 曾长育, 李红中, 等). Geological Bulletin of China(地质通报), 2012, 31(2-3): 486. [2] Li Hongzhong, Zhai Mingguo, Zhang Lianchang, et al. The Scientific World Journal, 2013, 2013: 949603. [3] CHEN Fu-wen, LI Hua-qin, WANG Deng-hong, et al(陈富文, 李华芹, 王登红, 等). Acta Geologica Sinica(地质学报), 2012, 86 (8): 1298. [4] LIANG Jin, ZHOU Yong-zhang, LI Hong-zhong, et al(梁 锦, 周永章, 李红中, 等). Acta Petrological Sinica(岩石学报), 2012, 28 (10): 3361. [5] MAO Jing-wen, CHEN Mao-hong, YUAN Shun-da, et al(毛景文, 陈懋弘, 袁顺达, 等). Acta Geologica Sinica(地质学报), 2011, 85(5): 636. [6] Noons R E, Devonshire R, Clapp T V, et al. Journal of Non-Crystaline Solids, 2008, 354: 3059. [7] LI Hong-zhong, ZHOU Yong-zhang, YANG Zhi-jun, et al(李红中,周永章,杨志军,等). Journal of Jilin University·Earth Science Edition(吉林大学学报·地球科学版), 2011, 41(3): 715. [8] Li Hongzhong, Zhai Mingguo, Zhang Lianchang, et al. The Scientific World Journal, 2014, 2014: 780910. [9] Yang Zhijun, Li Hongzhong, Peng Mingsheng, et al. Chinese Science Bulletin,2008, 53(1): 137. [10] Champagnon B, Panczer G, Chemarin C, et al. Journal of Non-Crystaline Solids, 1996, 196: 221. [11] Arguirov T, Mchedlidze T, Akhmetov V D, et al. Applied Surface Science, 2007, 254: 1083. [12] LI Hong-zhong , YANG Zhi-jun, ZHOU Yong-zhang, et al(李红中,杨志军,周永章,等). Earth Science—Journal of China University of Geoscience(地球科学—中国地质大学学报), 2009, 34(2): 299. [13] Frost R L, Erickson K L, Weier M L, et al. Journal of Molecular Structure, 2005, 737: 173. [14] Gunasekaran S, Anbalagan G. Spectrochimica Acta Part A: Molecular and Biomol Ecular Spectroscopy, 2007, 68(3): 656. [15] Meinert L D, Dipple M G, Nicolescu S. Economic Geology, 2005, 299. [16] KE Yi-kan, DONG Hui-ru(柯以侃,董慧茹). Analysis Chemistry Vol.3: Analysis Spectrum 2nd ed(分析化学手册第二版第三分册:光谱分析). Beijing: Chemical Industry Pres(北京: 化学工业出版社), 1998. 1324.Study on Mineralogical Characteristics of Quartz and Calcite from