Abstract:Long persistent phosphoresceoce CaAl2O4:Eu2+, Nd3+ nanoparticles were synthesized through sol-gel method. The structures and properties of the samples were analyzed by DTA, TGA, XRD, TEM and spectrometer. Results indicated that the CaAl2O4 crystalline phase was formed at 800 ℃. The particles are spherical in shape and about 20-40 nm in size. The peaks of the excitation, emission and thermoluminescence spectra shift compared with the CaAl2O4:Eu2+, Nd3+ coarse crystals. The luminescence decay includes a initial rapid part and a following slow part. The decay time lasts for about 5 h.
张希艳,姜薇薇,刘 学,卢利平,王晓春,柏朝晖,刘全生,曹志峰 . CaAl2O4:Eu2+, Nd3+纳米粉体的合成与发光性质 [J]. 光谱学与光谱分析, 2005, 25(10): 1560-1563.
ZHANG Xi-yan, JIANG Wei-wei, LIU Xue, LU Li-ping, WANG Xiao-chun, BAI Zhao-hui, LIU Quan-sheng, CAO Zhi-feng . Preparation and Characterization of CaAl2O4:Eu2+, Nd3+ Nanoparticles . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(10): 1560-1563.
[1] ZHANG Tian-zhi, SU Qiang, WANG Shu-bin(张天之, 苏 锵, 王淑彬). Chin. J. Lumin.(发光学报), 1999,20(2): 170. [2] LIN Yuan-hua, ZHANG Zhong-tai, TANG Zi-long, et al(林元华, 张中太, 唐子龙, 等). J. Materials Engineering(材料工程), 2001, 8: 29. [3] Su Qiang. CN Patent, 02117958, 1. [4] Bhargava R N, Gallagher D, Hong X, et al. Phy. Rev. Lett., 1994, 72: 416. [5] ZHAI Yong-qing, YAO Zi-hua, QIU Man-de, LIU Bao-sheng, WANG Kai-xiao, WANG Ying-jin(翟永清,姚子华,仇满德, 刘保生, 王凯肖, 王迎进). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(2): 236. [6] ZHANG Xi-yan(张希艳). Ph. D. Dissertation of Changchun University of Science and Technology(长春理工大学博士论文), 2003. [7] YU Jiang-bo, YUAN Xi-ming, CHEN Jing-zhong(于江波,袁曦明,陈敬中). Mater. Rev.(材料导报), 2001, 15(1): 30. [8] SONG Qing-mei, CHEN Ji-yao, WU Zhong-ya(宋庆梅,陈暨耀,吴中亚). J. of Fuda University(Natural Science)(复旦学报·自然科学版), 1995, 34(1): 103.