Abstract:Determination of arsenic in pure aluminum by inductively coupled plasma atomic emission spectrometry was interfered by aluminum matrix. The experiment showed that when the mass concentration of Al was greater than or equal to 5 000 times the As in the test solution, the measurement error was greater than 5%. In order to eliminate the interference, strong acid cation exchange fiber (SACEF) was used as solid phase extraction agent to adsorb Al3+. The extraction conditions included amount of SACEF, extraction time, temperature and pH were investigated. The optimal extraction conditions were that 0.900 0 g SACEF was used to extract the aluminum from the sample solution of pH 2.0 at 55 ℃ for 5 min with the ultrasonic assist, and in this case, the arsenic in the form of arsenic acid was not extracted and left in the solution for the determination. The results showed that after treating 10.00 mL test solution containing 1.00 μg arsenic and 20.0 mg aluminum, arsenic did not lose. The mass concentration of residual aluminum in the raffinate was about 2 000 times the As, which had not interfered the determination of arsenic. The detection limit (3 s) was 0.027 μg·mL-1 and quantification limit (10 s) was 0.091 μg·mL-1. The proposed method was successfully applied to the separation and determination of arsenic in the synthetic samples, the aluminum cans and the barbecue aluminum foil. Recovery was in the range of 98.3%~105% and RSD (n=3) was in the range of 0.1%~4.3%. The results showed that the content of arsenic in the aluminum cans and the aluminum barbecue foil was below the limited value of national standard (GB/T 3190—2008).
覃文霞,龚 琦*,李 敏,邓立新,莫利书,李艳琳 . 超声辅助固相萃取分离/ICP-AES测定食品包装铝材中砷的研究 [J]. 光谱学与光谱分析, 2015, 35(04): 1043-1047.
QIN Wen-xia, GONG Qi*, LI Min, DENG Li-xin, MO Li-shu, LI Yan-lin . Determination of Arsenic in Food Package Aluminum by Ultrasound Assisted Solid Phase Extraction/ICP-AES. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(04): 1043-1047.
[1] GB/T 3190—2008. Wrought Aluminum and Aluminum Alloy——Chemical Composition (变形铝及铝合金化学成分). Beijing:Standards Press of China(北京:中国标准出版社),2008. [2] Hassler J, Barth P, Richter S, et al. Journal of Analytical Atomic Spectrometry, 2011, 26(12): 2404. [3] CHENG Yong, YUAN Jin-hong, PENG Hui-xian(成 勇,袁金红,彭慧仙). Chinese Journal of Inorganic Analytical Chemistry(中国无机分析化学), 2013, 3(4): 52. [4] Palkendo J A, Kovach J, Betts T A. Journal of Chemical Education, 2014, 91(4): 579. [5] Wei Y H, Zhang J Y, Zhang, D W, et al. Food Chemistry, 2014, 159: 507. [6] Gong Q, Wei X L, Wu J N, et al. Journal of Analytical Atomic Spectrometry, 2012, 27(11): 1920. [7] ZHOU Xi-lin, ZHANG Hong, WANG Ya-sen, et al(周西林,张 宏,王亚森,等). Metallurgical Analysis(冶金分析), 2013, 33(4): 64. [8] Matsumiya H, Sakane Y, Hiraide M. Analytica Chimica Acta, 2009, 653(1): 86. [9] Cheng Y. Applied Mechanics and Materials, 2013, 271: 222. [10] HU Xuan, LI Yue-ping, SHI Lei(胡 璇,李跃平,石 磊). Metallurgical Analysis(冶金分析), 2014, 34(4): 17. [11] Wiltsche H, Günther D. Analytical and Bioanalytical Chemistry, 2011, 399(6): 2167. [12] Kovacs R, Schlosser S, Staub S P, et al. Journal of Analytical Atomic Spectrometry, 2009, 24(4): 476. [13] ZHANG Xiao-hong, HANG Wei, LI Qing-ping(张小红,杭 薇,李庆平). Liferatue and Information on Preventine Medicine(预防医学文献信息), 2004, 10(1): 68. [14] ZHI Hong-feng, SUN Ye, YANG Liu-hua(支红峰,孙 烨,杨柳桦). Chinese Journal of Health Laboratory Technology(中国卫生检验杂志), 2011, 21(9): 2172. [15] ZHANG Lin, LE Ai-shan, WANG Chang-zhao, et al(张 遴,乐爱山,王昌钊,等). Physical Testing and Chemical Analysis Part B: Chemical Analysis(理化检验-化学分册), 2009,45(10): 1197.