Development of Raman Spectroscopy Study of Fluid Inclusions
YANG Dan, XU Wen-yi
Ministry of Land Resources Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China
Abstract：In the present paper, the exploration process of the laser Raman analysis of fluid inclusions was reviewed and summarized. The authors tried to outlook the future research work on laser Raman analysis of fluid inclusions at low and room temperature. Research work at low temperatures:(1)Common multiple salt systems in the fluid inclusions; (2)Trying qualitative and quantitative analysis of ingredients in natural fluid inclusions; (3)Microthermometry considered first melting temperature as the eutectic temperature, and this view was suspected, so further research is needed; (4)chloride hydrate structure is inconclusive at low temperatures. Research work at room temperatures: (1) how Fe3+, Zn2+, Cu2+ and other ions being considered as the main metal ions of mineralization combine with Cl-and H2O are how to combine; (2) The reason for different concentrations of NaCl, CaCl2, MgCl2, CuCl2, ZnCl2, FeCl3 solution resulting in the shift of Raman OH stretching region (2 800～3 800 cm-1).
杨 丹, 徐文艺. 激光拉曼光谱测定流体包裹体成分研究进展 [J]. 光谱学与光谱分析, 2014, 34(04): 874-878.
YANG Dan, XU Wen-yi . Development of Raman Spectroscopy Study of Fluid Inclusions . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(04): 874-878.
[1] Thompson A B. Nature, 1992, 358: 295. [2] Bell D R. Rossman G R. Science, 1992, 255: 1391. [3] Ahrens T J. Nature, 1989, 342: 122. [4] Pawley A R. Holloway J R. Science, 1993, 260: 664. [5] Dubois M. Weisbrod A. Shtuka A. Chem. Geol., 1994, 115: 227. [6] Seward T M. Henderson C M B. Charnock J M. et al. Geochim. Cosmochim. Acta, 1999, 63(16): 2409. [7] Tackley P J. Science, 2000, 288(5473): 2002. [8] Audetat A, Gunther D, Heinrich C A. Science, 1998, 279: 2091. [9] Heinrich C A, Ryan C C, Mernagh T P, et al. Econ. Geol., 1992, 87: 1566. [10] Heinrich C A，Gunther D，Audetat A，et al. Geology，1999, 27: 755. [11] Lowenstern J B，Mahood G A，Rivers M L，et al. Science，1991, 252: 1405. [12] Rosasco G J, Roedder E, Simmons J H. Science, 1975, 190: 557. [13] Dhamelincout P, Schbnel H J. Rev. Gemmol.(Ass. Fr. Gemmol.), 1977: 52. [14] Rosasco G J, Roedder E. Geochim. Cosmochim. Acta, 1979, 43: 1907. [15] Dhamelincout P, Beny J M, Dubessy J. Bull Mineral., 1979, 102: 600. [16] Schrotter H W, Klockner H W. Raman Spectroscopy of Gases and Liquids. Springer-Verlag, Berlin, 1979. 123. [17] I-Ming Chou, Jill Dill Pasteris, Jeffery C Seitz. Geochim. & Cosmochim. Acta, 1990, 54: 535. [18] Beny C, Guilhaumou N, Tuoray J C. Chem. Geol., 1982, 37: 113. [19] Pasteris J D, Kuehn C A, Bodnar R J. Econ. Geol., 1986, 81: 915. [20] Burke E A J, Lustenhouwer W J. Chem. Geol., 1987, 61: 11. [21] Wopenka B, Pasteris J D. Appl. Spectrosc., 1986, 40: 144. [22] Wopenka B, Pasteris J D. Anal. Chem., 1987, 59: 2165. [23] Seitz J C, Pasteris J D, Wopenka B. Geochim. Cosmochim. Acta, 1987, 51: 1651. [24] Pasteris J D, Wopenka B, Seitz J C. Geochim. Cosmochim. Acta, 1988, 52: 979. [25] Kerkhof A M. 1988, 111: 257. [26] Dubessy J, Pagel M , Beny J M, et al. Geochim. Cosmochim. Acta, 1988, 52: 1155. [27] Dubessy J, Poty B, Ramboz C. Eur. J. Mineral., 1989, 1: 517. [28] Murphy P J, Roberts S. Arch. Mineral., 1993, 49(1): 152. [29] Fabre D, Oksengorn B. Appl. Spectrosc., 1992, 46: 468. [30] Ernst A. J. Burke. 2001. Lithos. 55(1-4): 139. [31] Roedder E. US Geol Survey Prof Paper, 1972, 440 JJ: 164. [32] Roedder E. Mineral Soo Amer, Reviews in Mineralogy, 1984, 12: 644. [33] ZHANG Wen-huai，CHEN Zi-ying(张文淮, 陈紫英). Fluid Inclusions Geology(流体包裹体地质学). Wuhan: China University of Geosciences Press(武汉: 中国地质大学出版社), 1993. 157. [34] Crawford M L. Phase Equilibria in Aqueous Fluid Inclusion . In: Hollister L S. Crawford M L. eds. Fluid inclusion: Applications to Petrology, Min Assoc Canada Short Course Handbook. Calgary: Albeta., 1981, 6: 157. [35] Goldstein R H, Reynolds T J. Syntematics of Fluid Inclusions in Diagenetic Minerals. In: S E P M Short Course. Tulsa: Oklahoma, 1994, 31: 1. [36] Davis D W. Lowenstern T K, Spencer R J. Geochim Cosmochim Acta, 1990, 54: 591. [37] Audetat A. Acta Petrologica Sinica(岩石学报), 2000, 16: 715. [38] Kreulen R. Chem. Geol., 1987, 61: 59. [39] Mernagh T P , Wilde A R. Geochim. Cosmo-him. Acta, 1989, 53: 765. [40] Winter C J, Roberts S. Arch. Mineral., 1993, 49(1): 246. [41] Grishina S, Dubessy J, Kontorovich A, et al . Eur. J . Mineral., 1992, 4: 1187. [42] Samson I M, Walker R T. Can. Mineral., 2000, 38: 35. [43] NI Pei，DING Jun-ying，RAO Bing(倪 培，丁俊英，饶 冰). Chinese Science Bulletin(科学通报)，2006，51(9)：1073. [44] Tao N J，Li G，Chen X，et al. Phys. Rev., 1991，A44: 6665. [45] Mcmilla P F，Jakobsson J R，Holloway J R，et al. Geochim. Cosmochim. Acta, 1983，47: 1937. [46] Mcmilla P F，Remmele R L. Am. Mineral．, 1986，71: 772. [47] Mysen B O ，Virgo D . In Advances in Materials Characterization Ⅱ. Plenum Publishing Corp.，New York，N.Y 4.3. [48] Walrafen G E. Chem. Phys., 1962，36: 1035. [49] Walrafen G E. Chem. Phys., 1964，40: 3249. [50] Walrafen G E . In Water，a Comprehensive Treatise.1. The Physics and Physical Chemistry of Water. New York: Plenum Press，N.Y 151. [51] Roedder E. Fluid inclusions. Rev. Mineral. 12. [52] Dubessy J, Boiron M C, Mossette A, et al. Eur. Mineral., 1992, 4: 885. [53] Beny C, Feofanov A. Arch. Mineral., 1993, 49(1): 27. [54] Lü Xin-biao，YAO Shu-zhen，HE Mou-chun(吕新彪，姚书振，何谋春). Earth Science Frontiers(地学前缘)，2001，8(4)：429. [55] CHEN Yong, ZHOU Yao-qi, ZHANG Da-gang(陈 勇，周瑶琪，章大港). The Journal of Light Scattering(光散射学报)，2002，14(4)：216. [56] DING Jun-ying, NI Pei, RAO Bing，et al(丁俊英，倪 培，饶 冰，等). Geological Review(地质论评)，2004，50(2)：203. [57] ZOU Xiao-yan, Lü Xin-biao, HE Mou-chun(邹晓艳，吕新彪，何谋春). Rock and Mineral Analysis(岩矿测试)，2007，26(1)：26. [58] Falk M，Knop O. Water in stoichiometric hydrates . In water，a Comprehensive Treatise. 2. Water in Crystalline Hydrates Aqueous Solutions of Simple Nonelectrolytes. New York: Plenum Press，1973. 55. [59] Dubessy J，Audeoud D，Wilkins R，et al . Chemical Geology，1982，37: 137. [60] YANG Dan, XU Wen-yi(杨 丹，徐文艺). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2013，33(2): 376.
