1. Key Laboratory of Mineral Luminescent Material and Microstructure of Xinjiang, Xinjiang Normal University, Urumqi 830054, China 2. Xinjiang Yili Normal College, Yining 835000, China
Abstract:Na8Al6Si6O24Cl2∶Mn and Na8Al6Si6O24Cl2∶Fe NIR phosphors were prepared by a solid-solid reaction at high temperature. Their crystal structures of fluorescent powder were investigated by using X-ray powder diffraction (XRD), and their NIR emission spectrum and excitation spectrum were measured at room temperature. The main emission peak of Mn5+ in the Na8Al6Si6O24Cl2∶Mn phosphor was observed at 1 200 nm in the NIR spectral region under 400 or 602 nm excitation, attributing to the 3A2—3T2 and 3A2—1E transitions of Mn5+ ions. The characteristic NIR luminescence of Mn5+ in sodalite is greatly enhanced by co-doping manganese and sulfur. A mechanism of the energy transfer between S-2 and Mn5+ was also proposed here. The main emission peak of Fe2+ ions in the Na8Al6Si6O24Cl2∶Fe phosphor was recorded at 1 000 nm in the NIR region under the excitation of 334 or 500 nm. This photoluminescence originated from the 3T1—5E transition of Fe2+. Such an emission in the NIR region suggests a potential application in improving solar spectrum to enhance the efficiency of silicon solar cells.
[1] Gaft M, Panczer G, Nagli I, et al. Physics and Chemistry of Minerals, 2009, 36: 127. [2] VanDoorn C Z, Schipper D J. Physics Letters, 1971, 34A: 139. [3] Aierken Sidike, Alifu Sawuti, Wang Xiangming, et al. Physics and Chemistry of Minerals, 2007, 34: 477. [4] Tuerxun Aidilibike, Bahetiguli Asilibieke, Guzaliayi Juman, et al(吐尔逊·艾迪力比克, 巴合提古丽·埃斯里别克, 古扎丽阿艺·居曼,等). Journal of Xinjiang Normal University(新疆师范大学学报), 2012, 4: 86. [5] Deng Kaimo, Gong Tao, Hu Lingxun. Opt. Exp., 2011, 19: 1749. [6] Deng Kaimo, Wei Xiantao. Applied Physics B, 2011, 102: 555. [7] Ajo D, Favaro M L, Pozza G. Journal of Materials Science, 1997, 32: 4217. [8] YAN Shou-xun, ZHANG Bing, ZHAO Yong-chao, et al(燕守勋,张 兵,赵永超, 等). Remote Sensing Technology and Application(遥感技术与应用), 2003,18: 191. [9] HUANG Shi-hua, LOU Li-ren(黄世华,楼立人). Chinese Journal of Luminescence(发光学报),2008, 29(4): 646.