Abstract:In order to further understand the association between cellulose and lignin in gymnosperm plant, carbohydrate part of the lignin-carbohydrate complexes was analyzed. Cellulose precursor i.e.(6-13C)uridine diphoshphate glucose, was synthesized, and injected into a living ginkgo tree with lignin inhibitor AOPP and exogenous lignin precursor. The results from the determination of 13C abundance indicate that the deposition of cellulose in the cell wall is very fast and effective in the primary wall. The analysis of high resolution solid nuclear magnetic 13C NMR spectra confirms that the bonds between C6 position of glucose units in cellulose and α-carbons of lignin side chain are benzyl ether linkage.
向松明1,谢益民*,杨海涛,姚 兰 . 纤维素13C同位素示踪法研究纤维素与木素连接方式 [J]. 光谱学与光谱分析, 2013, 33(09): 2488-2491.
XIANG Song-ming, XIE Yi-min*, YANG Hai-tao,YAO Lan . Analysis of the Association between Cellulose and Lignin by Carbon 13 Tracer Method . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(09): 2488-2491.
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