Abstract:A novel enhanced ultraviolet absorption spectrometry method was developed for the quantitative analysis of SDBS induced by β-cyclodextrin(β-CD) with strong interferences. The ultraviolet absorption spectra of SDBS indicated that the presence of β-CD could result in the enhancement of absorption intensities of SDBS. A good linearity was obtained between the UV-absorption intensity of the system and the concentration of SDBS. The results indicated that the determination precision and the determination ranges of SDBS could be greatly improved by β-CD. The effect of several common interfering substances(SDS, OP-10, HPAM) on the determination of SDBS could be significantly reduced in β-CD aqueous solution. Therefore, the maximum errors of the determined SDBS were less than 2.0% under multifactor interferences, and the precision of the method was also as high as 10-2~10-3 mg·L-1. The stable inclusion of β-CD and SDBS could be automatically formed in water with molar ratio of 1:1. The stability constant of the inclusion, Ka, was 87 and the standard Gibbs function of molar reaction, ΔγGmΘ(298 K), was -11.064 kJ·mol-1. FTIR analysis exhibited that SDBS could be induced by β-CD since the phenyl group in SDBS molecule could exist stably in the cavity of β-CD and form the inclusion.
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