Abstract：To improve the precision and accuracy of elements and isotopes analysis in traditional Ar-ICP, the addition of nitrogen in ICP has been widely used. The present review focused on the discussions of the basic physical and chemical properties of the Ar-N2 mixed gas inductively coupled plasma and the mechanisms of the special nature of Ar-N2 mixed gas plasma. The applications of Ar-N2 inductively coupled plasma in spectral analysis and mass spectrometry analysis in the past 40 years were summarized. The authors also give an overall outlook on the application of this technology.
Key words：Addition of nitrogen;Ar-N2 mixed gas inductively coupled plasma;Properties of physical and chemistry;Mechanisms
刘圣华，陈 涛，李 珍，王立云，刘勇胜，胡圣虹，胡兆初* . 氩-氮混合气电感耦合等离子体在元素和同位素分析中的应用进展 [J]. 光谱学与光谱分析, 2013, 33(07): 1936-1942.
LIU Sheng-hua, CHEN Tao, LI Zhen, WANG Li-yun, LIU Yong-sheng, HU Sheng-hong, HU Zhao-chu* . Application of Argon-Nitrogen Mixed Gas Inductively Coupled Plasma in Elements and Isotopes Analysis . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(07): 1936-1942.
[1] Seo J H, Guillong M, Aerts M, et al. Chem. Geol., 2011, 284(1): 35. [2] Zhu Y, Inagaki K, Haraguchi H, et al. J. Anal. At. Spectrom., 2010, 25(3): 364. [3] Hu Z C, Gao S, Liu Y S, et al. J. Anal. At. Spectrom., 2008, 23(8): 1093. [4] Xiao G, Beauchemin D. J. Anal. At. Spectrom., 1994, 9(4): 509. [5] Craig J M, Beauchemin D. J. Anal. At. Spectrom., 1992, 7(6): 937. [6] Gray A L, Williams J G. J. Anal. At. Spectrom., 1987, 2(6): 599. [7] Greenfield S, Jones I L, McGeachin H M, et al. Anal. Chem. Acta, 1975, 74(2): 225. [8] Tanner S D. J. Anal. At. Spectrom., 1995, 10(11): 905. [9] Branch S, Ebdon L, Ford M, et al. J. Anal. At. Spectrom., 1991, 6(2): 151. [10] Munro S, Ebdon L, McWeeny D J. J. Anal. At. Spectrom., 1986, 1(3): 211. [11] Louie H, Soo S Y. J. Anal. At. Spectrom., 1992, 7(3): 557. [12] Sheppard B S, Shen W L, Davidson T M, et al. J. Anal. At. Spectrom., 1990, 5(8): 697. [13] Evans E H, Ebdon L. J. Anal. At. Spectrom., 1989, 4(3): 299. [14] Hu Z C, Hu S H, Gao S, et al. Spectrochim. Acta Part B, 2004, 59(9): 1463. [15] Montaser A, Van Hoven R L, Barnes R M. Crit. Rev. Anal. Chem., 1987, 18(1): 45. [16] Sesi N N, Mackenzie A, Shanks K E, et al. Spectrochim. Acta Part B, 1994, 49(12-14): 1259. [17] Montaser A, Mortazavi J. Anal. Chem., 1980, 52(2): 255. [18] Montaser A, Fassel V A, Zalewski J. Appl. Spectrosc., 1981, 35(3): 292. [19] Choot E H, Horlic G. Spectrochim. Acta Part B, 1986, 41(9): 889. [20] Houk R S, Montaser A, Fassel V A. Appl. Spectrosc., 1983, 37(5): 425. [21] Lam J W, Horlick G. Spectrochim. Acta Part B, 1990, 45(12): 1313. [22] Durrant S F. Fresenius J. Anal. Chem., 1994, 349: 768. [23] Choot E H, Horlick G. Spectrochim. Acta Part B, 1986, 41(9): 907. [24] Wang J, Evans E H, Caruso J A. J. Anal. At. Spectrom., 1992, 7(6): 929. [25] Choot E H, Horlick G. Spectrochim. Acta Part B, 1986, 41(9): 935. [26] Bloxham M J, Worsfold P J, Hill S J. Analytical Proceedings including Analytical Communications，1994, 31(3): 95. [27] Ishii I, Golightly D W, Montaser A. J. Anal. At. Spectrom., 1988, 3(7): 965. [28] Montaser A, Ishii I, Palmer B A, et al. Spectrochim. Acta Part B, 1990, 45(6): 603. [29] Cai M, Haydar D A, Montaser A, et al. Spectrochim. Acta Part B, 1997, 52(3): 369. [30] Long G L, Brenner I B. J. Anal. At. Spectrom., 1990, 5(6): 495. [31] Wagatsuma K, Hirokawa K. Anal. Sci., 1993, 9(4): 509. [32] Wagatsuma K, Hirokawa K. Anal. Sci., 1994, 10(3): 469. [33] Witte T M, Houk R S. Spectrochim. Acta Part B, 2012, 69: 9. [34] Barnes R M, Nikdel S. Appl. Spectrosc., 1976, 30(3): 310. [35] Montaser A, Fassel V A. Appl. Spectrosc., 1982, 36(6): 613. [36] Haraldsson C, Lyven B, Ohman P, et al. J. Anal. At. Spectrom., 1994, 9(11): 1229. [37] van der Velde-Koerts T, de Boer J L M. J. Anal. At. Spectrom., 1994, 9(10): 1093. [38] Vaughan M-A, Horlick G, Tan S H. J. Anal. At. Spectrom., 1987, 2(8): 765. [39] Hill S J, Ford M J, Ebdon L. J. Anal. At. Spectrom., 1992, 7(5): 719. [40] Holliday A E, Beauchemin D. Spectrochim. Acta Part B, 2004, 59(3): 291. [41] Durrant S F. Fresenius J. Anal. Chem., 1993, 193(347): 389. [42] Sheppard B S, Caruso J A. J. Anal. At. Spectrom., 1994, 9(3): 145. [43] Ni Q, Hu Z C, Bao Z Y, et al. Chinese Chem. Lett., 2009, 20(1): 92. [44] Hu Z C, Liu Y S, Gao S, et al. J. Anal. At. Spectrom., 2012, 27(9): 1391. [45] Hirata T, Nesbitt R W. Geochim. Cosmochim. Acta, 1995, 59(12): 2491. [46] Iizuka T, Hirata T. Chem. Geol., 2005, 220(1-2): 121. [47] Liu Y S, Hu Z C, Zong K Q, et al. Chin. Sci. Bull., 2010, 55(15): 1535. [48] Crowe S A, Fryer B J, Samson I M, et al. J. Anal. At. Spectrom., 2003, 18(11): 1331. [49] Shaheen M, Fryer B J. J. Anal. At. Spectrom., 2010, 25(7): 1006. [50] Leite T D F, Escalfoni Jr R, da Fonseca T C O, et al. Spectrochim. Acta Part B, 2011, 66(5): 314. [51] Hu Z C, Liu Y S, Li M, et al. Geostand. Geoanal. Res., 2009, 33(3): 319. [52] Nesbitt R W, Hirata T, Butler I B, et al. Geostand. Newsl., 1997, 21(2): 231. [53] Balsanek W J, Ertas G, Holcombe J A. Spectrochim. Acta Part B, 2006, 61(6): 732. [54] Guillong M, Heinrich C A. J. Anal. At. Spectrom., 2007, 22(12): 1488. [55] Evans E H, Ebdon L. J. Anal. At. Spectrom., 1990, 5(6): 425. [56] Beauchemin D, Craig J M. Spectrochim. Acta Part B, 1991, 46(5): 603. [57] Lam J W, McLaren J W. J. Anal. At. Spectrom., 1990, 5(6): 419. [58] Holliday A E, Beauchemin D. J. Anal. At. Spectrom., 2003, 18(9): 1109. [59] Laborda F, Baxter M J, Crews H M, et al. J. Anal. At. Spectrom., 1994, 9(6): 727. [60] Hattendorf B, Latkoczy C, Günther D. Anal. Chem., 2003, 75(15): 341. [61] Koch J, Günther D. Appl. Spectrosc., 2011, 65(5): 155. [62] Novotny I, J C F, Wan Jialiang, et al. Mermet. Spectrochim. Acta Part B, 1996, 51: 1517. [63] Vanhaecke F, Dams R, Vandecasteele C. J. Anal. At. Spectrom., 1993, 8(3): 433. [64] Hilsenrath J, Beckett C W, Benedict W S, et al. US Government Printing Office, 1955: 564. [65] Boumans P W J M, De Boer F J. Spectrochim. Acta Part B, 1977, 32(9-10): 365. [66] Barnes R M, Schleicher R G. Spectrochim. Acta Part B, 1981, 36(2): 81. [67] Chan G C Y, Hieftje G M. Spectrochim. Acta Part B, 2004, 59(2): 163.
