Abstract:The total partition function was calculated for carbon monoxide with approximation. Using the dipole moment function and the wave function with Morse approximation, we computed the matrix elements of vibrational-rotational transition and absorption coefficient at normal and high temperature. The computed results agreed with the HITRAN database and literature, which shows that the calculation of total partition function and matrix elements of vibrational-rotational transition is reliable. Furthermore, the absorption coefficient and radiant spectrum are also presented at higher temperature of 4 000 and 6 000 K.
Key words:Spectrum;Carbon monoxide;Total partition function;Matrix elements of vibrational-rotational transition;Absorption coefficient
齐新华,苏 铁,杨富荣,鲍伟义,陈 力 . 高温下CO分子的振转跃迁光谱 [J]. 光谱学与光谱分析, 2013, 33(02): 300-303.
QI Xin-hua, SU Tie, YANG Fu-rong, BAO Wei-yi, CHEN Li . Vibrational and Rotational Spectrum of Carbon Monoxide at High Temperature. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(02): 300-303.
[1] Lassettre E N. Journal of Chem., 1969, 47: 1733. [2] Klump K N, Lassettre E N. Journal of Chem. Phys., 1974, 60: 4830. [3] YANG Han-song, FAN Si-lin, LI Hai(杨汉嵩,范嗣林,李 海). Journal of Huaibei Coal Industry Teachers College(淮北煤炭师范学院学报),2005, 26: 31. [4] CHEN Ya-feng, ZENG Qin, MAO Rui-qing, et al(陈亚峰,曾 琴,毛瑞青,等). Progress in Astronomy(天文学进展), 2000, 18: 67. [5] Chackerian C,Tipping R H. Journal of Molecular Spectrosc.,1983, 99: 431. [6] Zou Q, Varanasi P J. Quant. Spectrasc. Radiat. Transfer.,2002, 75: 63. [7] Rothman L S, Gordon I E, Barbe A, et al. J. Quant. Spectrasc. Radiat. Transfer., 2009, 110: 533. [8] Churchill D R, Hagstrom S A, Landshoff R K M. J. Quant. Spectrasc. Radiat. Transfer.,1964, 4: 291. [9] Gerhard Herzberg(G. 赫兹堡). Molecular Spectra and Molecular Structure:1st ed.(分子光谱与分子结构:第1卷). Translated by WANG Ding-chang(王鼎昌,译). Beijing: Science Press(北京:科学出版社), 1983. [10] ZHANG Zhong-ming, XIONG Ye, LIN Li-zhong(张中明,熊 烨,林理忠). Acta Optica Sinica(光学学报), 1998, 18: 286. [11] Bouanich J P,Blumenfeld L. J. Quant. Spectrasc. Radiat. Transfer.,1986, 36: 87. [12] Ludwig C B, Malkmus W, Reardon, J E, et al. Handbook of Infrared Radiation from Combustion Gases, NASA, 1973.