Abstract：The rapid pyrolysis of GAP/AP system under simulated combustion conditions was investigated by an on-line analysis, i.e. so called T-Jump/FTIR. The results show that the compositions of the main gaseous products for pyrolysis are changed, in comparison with the pyrolyses of single, which indicates that the interactions occur between the components of GAP/AP system. From an obvious effect of pressure on the main gaseous products for GAP/AP pyrolysis it is shown that the interactions between GAP and AP components arise from the gaseous products of AP and both the reactions in gas phase and in gas/condensed phase occur in the GAP/AP mixed system. The interactions between GAP and AP are not affected by test temperature. It is considered that the real time analysis of gaseous products of energetic material pyrolysis under simulated combustion conditions would be carried out by T-Jump/FTIR on-line analysis technique and from microcosmic reaction a technical approach used to explore the rapid pyrolysis of energetic materials and interactions between their components at high temperature and pressure would be developed by the on-line analysis technique from microcosmic reaction.
张腊莹，刘子如，王晓红，衡淑云，邵颖慧，丁 黎 . 傅里叶红外光谱法研究GAP/AP混合体系的快速热裂解 [J]. 光谱学与光谱分析, 2013, 33(01): 14-18.
ZHANG La-ying, LIU Zi-ru, WANG Xiao-hong, HENG Shu-yun, SHAO Ying-hui, DING Li . An Investigation of Fast Thermolysis of GAP/AP System by FTIR Spectroscopy. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(01): 14-18.
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