Study on Far-Infrared Reflectivity Spectra of Microwave Dielectric Ceramic (RbBi)1/2MoO4
WANG Qiu-ping1,2, LIU Han-chen1
1. School of Science, Xi’an Polytechnic University, Xi’an 710048, China 2. Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi’an Jiaotong University, Xi’an 710049, China
Abstract:The (RbBi)1/2MoO4 ceramic was prepared via solid state reaction method. The room temperature far-infrared reflectivity spectra were measured and 15 vibration modes were observed. Kramers-Kronig (K-K) relationship was employed to fit infrared spectra. The optical frequency permittivity ε∞ is equal to 2.17 for the dielectric materials, and the extrapolated value to microwave frequency (at about 9 GHz) is 20.56 and it is slightly smaller than the actual measured value ~21.4. The calculated value of quality factor (Q×f) is 11 790 GHz, which is higher than the actual measured value ~6 200 GHz, and it can be deduced that the quality factor of the (RbBi)1/2MoO4 ceramic material has large room for improvement.
王秋萍1,2,刘汉臣1 . (RbBi)1/2MoO4陶瓷微波介电性能的远红外反射谱研究 [J]. 光谱学与光谱分析, 2012, 32(09): 2382-2384.
WANG Qiu-ping1,2, LIU Han-chen1. Study on Far-Infrared Reflectivity Spectra of Microwave Dielectric Ceramic (RbBi)1/2MoO4. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(09): 2382-2384.
[1] Sebastian M T, Jantunen H. Int. Mater. Rev., 2008, 53(2):57. [2] Reaney I M, Iddles D. J. Am. Ceram. Soc., 2006, 89(7): 2063. [3] Scotta R I, Thomas M, Hampson C. J. Eur. Ceram. Soc., 2003, 23:2467. [4] Jancar B, Suvorov D, Valant M, et al. J. Eur. Ceram. Soc., 2003, 23:1391. [5] Choi G K, Kim J R, Yoon S H, et al. J. Eur. Ceram. Soc., 2007, 27(8): 3063. [6] Zhou Di, Wang Hong, Pang Lixia, et al. J. Am. Ceram. Soc., 2009, 92(10): 2242. [7] Zhou Di, Wang Hong, Yao Xi, et al. J. Am. Ceram. Soc., 2008, 91(10): 3419. [8] Zhou Di, Randall C A, Pang Lixia, et al. Mater. Chem. Phys., 2011, 129: 688. [9] Alford N M, Penn S J. J. App. Phys., 1996, 80(10): 5895. [10] Klevtsov P V, Vinokurov V A. Neorg. Mater., 1973, 9: 156. [11] Hanuza J, Maczka M. Vibrational Spectroscopy, 1994, 7: 85.