A Method for Determination of Trace Naphthalene and Phenanthrene in Water Using Constant-Wavelength Synchronous Fluorescence Spectrometry
SONG Guang-qing1, 2, XI Hong-bo1, ZHOU Yue-xi1*, LI Jie2, ZHAO Jing-tian3, CUI Jun-hua3
1. Research Center of Water Pollution Control Technology, Chinese Research Academy of Environmental Sciences, Beijing 100012, China 2. Environmental & Municipal Engineering Department, Lanzhou Jiaotong University, Lanzhou 730070, China 3. College of Urban Construction, Hebei University of Engineering, Handan 056038, China
Abstract:In view of synchronous fluorescence possessing the character of good selectivity, high sensitivity, less interference, etc. it can be used for simultaneous determination of multi-component mixtures of polycyclic aromatic hydrocarbons(PAHs). A new method of constant-wavelength synchronous fluorescence spectrometry to determine two naphthalene and phenanthrene of PAHs was developed in this study. The effect of different experimental conditions, such as different disolvents for character of fluorescence spectra and the choose of the optimal wavelength difference were studied. Experiment showed that the simultaneous indentification and quantitative determination of the two PAHs when Δλ=100 was chosen. The fluorescence intensity was linearly related to naphthalene and phenanthrene concentration in the range of 0.5~25.0 μg·L-1 with correlation coefficient 0.999 5 and 0.999 7, respectively. The detection limits were all lower than 0.03 μg·L-1, and the relative standard deviations for naphthalene and phenanthrene were 1.19% and 180%(n=7), respectively. Results show that the compounds can be analyzed qualitatively and quantitatively by synchronous fluorescence spectrometry.
宋广清1, 2,席宏波1,周岳溪1*,李 杰2,赵京田3,崔俊华3 . 同步荧光光谱法测定水中痕量萘和菲[J]. 光谱学与光谱分析, 2012, 32(07): 1838-1841.
SONG Guang-qing1, 2, XI Hong-bo1, ZHOU Yue-xi1*, LI Jie2, ZHAO Jing-tian3, CUI Jun-hua3 . A Method for Determination of Trace Naphthalene and Phenanthrene in Water Using Constant-Wavelength Synchronous Fluorescence Spectrometry. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(07): 1838-1841.
[1] LIU Zhi-chao, HU Xia-lin, LIU Jing-fu(刘志超, 胡霞林, 刘景富). Chinese Journal of Chromatography(色谱), 2010, 28(5): 513. [2] ZHANG Ling-jin, SU Jian-ru, ZHOU Li-jun, et al(张玲金, 苏建茹, 周立军, 等). Rock and Mineral Analysis(岩矿测试), 2003, 22(2): 113. [3] Chanbasha B, Jeffrey P O, Hian K L. Water Air & Soil Pollution, 2003, 149(1-4): 315. [4] XU Chuan, SHU Wei-qun, LUO Cai-hong, et al(许 川, 舒为群, 罗财红, 等). Research of Environmental Sciences(环境科学研究), 2007, 20(5): 57. [5] HU Guo-cheng, GUO Jian-yang, LUO Xiao-jun, et al(胡国成, 郭建阳, 罗孝俊, 等). Research of Environmental Sciences(环境科学研究), 2009, 22(3): 321. [6] FENG Yue-peng, PENG Hong-jun, LIANG Hong, et al(封跃鹏, 彭鸿俊, 梁 洪, 等). Research of Environmental Sciences(环境科学研究), 1998, 11(6): 39. [7] U.S. EPA Report No. EPA440/4-79-029, Washington, DC, 1979. [8] Maria R M, Santino O. Atmospheric Environment, 2008, 42(8): 1801. [9] Kelly S W, Jimmie D P, James N H, et al. Chemosphere, 2002, 49(7): 703. [10] WANG Xin-xin, LIU Qing-yang, LIU Yan-ju, et al(王欣欣, 刘庆阳, 刘艳菊, 等). Chinese Journal of Chramatography(色谱), 2010, 28(9): 849. [11] TANG Hua, CHEN Da-zhou, WU Xue, et al(汤 桦, 陈大舟, 吴 雪, 等). Journal of Chinese Mass Spectrometry Society(质谱学报), 2010, 31(4): 208. [12] Nieves B B, Roberto R G, Patricia P B, et al. Analytical Chimical Acta, 2011, 693(1-2): 62. [13] XU Jin-gou, WANG Zun-ben(许金钩, 王尊本). Fluorescence Analysis Method(Third Edition)(荧光分析法·第3版). Beijing Science Press(北京: 科学出版社), 2006. 137. [14] Well C F, Salam M A, Journal of the Chemical Society A, 1968, (1): 24. [15] Kohler G. Journal of Photochemistry, 1987, 38(2): 217. [16] U.S Environmental Protection Agency 1997 Guideline Establishing Test Procedures for the Analysis of Pollutants. U S Code of Federal Regulations, 1997. 265.