XPS and SEM Spectroscopy Study of Hyperdispersant on Atrazine Surface
XU Yan1, SUN Bao-li2, MA Chao1, ZHANG Ping1, CAI Meng-ling1, WU Xue-min1*
1. Department of Applied Chemistry, China Agricultural University, Key Laboratory of Pesticide Chemistry and Application, Ministry of Agriculture, Beijing 100193, China 2. Institute of Environment and Sustainable Development in Agriculture, Chinese Academy of Agricultural Sciences, Beijing 100081, China
摘要: 用X射线光电子能谱(X-ray photoelectron spectroscopy,XPS)研究了聚羧酸型梳状共聚物超分散剂吸附于莠去津颗粒样品表面的电子状态,计算了吸附厚度。结果表明,吸附分散剂后,莠去津颗粒界面的N(1s)和Cl(2p)谱峰强度明显减弱,Cl(2s)几乎消失,C(1s),O(1s)和Na(1s)谱峰强度则明显增强,这主要是分散剂中C,O和Na的贡献,且吸附分散剂后能在莠去津颗粒界面形成良好的吸附保护膜,其厚度约为24 nm。用扫描电子显微镜(scanning electron microscope,SEM)研究了样品表面形貌,研究发现吸附分散剂后莠去津颗粒变小、分布有序,使莠去津在水中能够获得稳定的悬浮性能。本文研究结果为莠去津环保剂型悬浮剂的应用提供了重要信息。
关键词:X射线光电子能谱;扫描电子显微镜;莠去津;超分散剂;吸附
Abstract:The authors studied the electronic condition of comb-shaped copolymer of polycarboxylic acid type hyperdispersant adsorbed on the surface of atrazine particles with X-ray photoelectron spectroscopy (XPS). The thickness of the adsorption was calculated. The results suggested that after adsorbing the dispersant, the peak intensity of N(1s) and Cl(2p) of the interface of atrazine particle decreased sharply, while the absorption of Cl(2s) almost diminished. Meanwhile the peak intensity of C(1s), O(1s) and Na(1s) increased obviously owing to the second emission of C, O, and Na from the dispersant molecule. After adsorption, the dispersant formed a favorable protecting membrane on the surface of atrazine particles whose thickness was about 24 nm. The authors also studied the surface state of the sample with scanning electron microscope (SEM). The results of which showed that after adsorption, the atrazine particles became smaller and their dispersion was in good order. These changes allowed the atrazine particle to have a stable suspension property. This study provided significant information for the application of environment friendly atrazine suspension concentrate.
Key words:X-ray photoelectron spectroscopy;Scanning electron microscope;Atrazine;Hyperdispersant;Adsorption
徐 妍1,孙宝利2,马 超1,张 平1,蔡梦玲1,吴学民1* . 超分散剂在莠去津颗粒表面吸附的XPS和SEM分析[J]. 光谱学与光谱分析, 2011, 31(09): 2569-2573.
XU Yan1, SUN Bao-li2, MA Chao1, ZHANG Ping1, CAI Meng-ling1, WU Xue-min1* . XPS and SEM Spectroscopy Study of Hyperdispersant on Atrazine Surface. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(09): 2569-2573.
[1] XU Yan, MA Chao, LIU Shi-lu, et al(徐 妍, 马 超, 刘世禄, 等). Modern Agrochemicals(现代农药), 2010, 9(2): 18. [2] Tadros Th F. Suspension Concentrates, United Nations Industrial Development Organization Vienna, 1998. 169. [3] Butt H J, Berger R, Bonaccurso E, et al. Advances in Colloid and Interface Science, 2007, 133(2): 91. [4] Yoshioka K, Sakai E, Daimon M, et al. J. Am. Cerma. Soc., 1997, 80(10): 2667. [5] XU Yan, SHENG Qi, ZHAN Rui, et al(徐 妍, 盛 琦, 战 瑞, 等). 7th China’s New Agrochemicals Development Seminar Hangzhou, 2007. 475. [6] QIN You-shan, LI Han-cheng, GAO Nan(秦友山, 李汉承, 高 楠). Modern Agrochemicals(现代农药), 2008, 7(6): 10. [7] Fetisova A V, Kuznetsovb M V. Journal of Applied Spectroscopy, 2009, 76(4): 523. [8] Ching-Ju Monica Chin, Mei-Wen Shih, Hen-Jer Tsai. Applied Surface Science, 2010, 256: 6035. [9] Amit R, Kunal K, Hugh H J. J. Colloid and Interface Sci., 2009, 332: 22. [10] Baran Jan A, Drozd Marek A, Ratajczak Henryk. Journal of Molecular Structure, 2010, 976: 226. [11] Toshihiro Isobe, Yosuke Nakano, Yoshikazu Kameshima, et al. Applied Surface Science, 2009, 255: 8010. [12] Tomlin C D S. The Pesticide Manual. 12th ed. The British Crop Protection Countil, 2000, 42. [13] WU Gang(吴 刚). Structure Characterization and Application of Material(材料结构表征与应用). Beijing: Chemical Industry Press(北京:化学工业出版社), 2002, 356.