Study on Spectra Properties of Novel Octa-Substituted Phthalocyanines
XIA Dao-cheng1, 2, 4, LI Wan-cheng3*, WANG Hong-fu1, 4，ZHENG Xin-xing1，GUO Yan-jie1，YANG Xu-qing1
1. College of Chemistry, Yuncheng University, Yuncheng 044000, China 2. College of Chemistry, Northeast Normal University, Changchun 130021, China 3. State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, China 4. College of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 041000, China
Abstract：The spectrum properties of four novel 1,4,8,11,15,18,22,25-octaoxybutyl copper phthalocyanine; 1,4,8,11,15,18,22,25-octamethoxybutanoate manganese phthalocyanine; 1,4,8,11,15,18,22,25-octamethoxybutanoate copper phthalocyanine; 1,4,8,11,15,18,22,25-octamethoxybutanoate zinc phthalocyanine were investigated by infrared, fluorescence and UV-visible spectrum in the the paper. There is no rule in the infrared spectrum of these octa-substituted phthalocyanines. The orders of the Q band, B band and Pc dimer band are different among the above Octa-substituted Phthalocyanines in the UV and fluorescence spectra. The reason is related to the interaction between the ligand and the central metal of these octa-substituted phthalocyanines.
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