The Spectroscopic Properties of a New Rhodamine B Schiff-Base Fluorescent Derivative
ZHANG Ling-fei1, ZHAO Jiang-lin1, ZENG Xi1, MU Lan1*, WEI Gang2
1. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China 2. CSIRO Materials Science and Engineering, P.O. Box 218, Lindfield, NSW 2070, Australia
Abstract：A derivative with Schiff-base structure was synthesized. Fluorescence and visible absorption spectra show that the presence of Fe3+ induces the formation of a Fe3+ complex, observing significant enhancement of fluorescence and absorption. The results show that the derivative is not only a good fluorescence and colorimetric chemosensor for Fe3+, but also a metal complex fluorescent probe for BSA.
Key words：Rhodamine B Schiff-base;Fluorescence and colorimetric chemosensor;Fe3+;BSA
[1] ZHAO Wen-feng, CHEN Lang-xing, HE Xi-wen, et al(赵文峰, 陈朗星, 何锡文, 等). Chemical Reagents(化学试剂), 2006, 28(5): 269. [2] Desvergne J P, Czarnik A W. Chemosensors for Ion and Molecule Recognition. Dordrecht: Kluwer，1997. [3] Amendola V, Fabbrizzi L, Forti F, et al. Coord Chem Rev., 2006, 250: 273. [4] Valeur B. Molecular Fluorescence: Principles and Applications. New York: Wiley-VCH Verlag GmbH, 2001. Chapter 10: 295. [5] Zheng X Y, Zhang W J, Mu L, et al. J. Incl. Phenom. Macrocycl. Chem.，2010, 68: 139. [6] ZENG Xi, WU Chong, DONG Lei, et al(曾 晞, 吴 翀, 董 蕾, 等). Sci. China Ser. B-Chem.(中国科学B辑), 2009, 4(52): 523. [7] Zeng X, Dong L, Wu C, et al. Sensors and Actuators B., 2009, 141: 506. [8] Wu C, Zhang W J, Zeng X, et al. J. Incl. Phenom. Macrocycl. Chem., 2010, 66: 125. [9] Dong L, Wu C, Zeng X, et al. Sensors and Actuators B., 2010, 145: 433. [10] Sumner J P, Kopelman R. Analyst., 2005, 130: 52. [11] Ma Y, Luo W, Quinn P J, et al. Med. Chem., 2004, 47: 6349. [12] Tumambac G E, Rosencrance C M, Wolf C. Tetrahedron., 2004, 60: 11293. [13] Xiang Y, Tong A J. Org. Lett., 2006, 8: 1549. [14] Lee M H, Wu J S, Lee J W, et al. Org. Lett., 2007, 9: 2501. [15] ZHANG Ling-fei, ZHAO Jiang-lin, ZENG Xi, et al(张玲菲, 赵江林, 曾 晞, 等). Chinese Journal of Inorganic Chemistry(无机化学学报), 2010, 26(10): 1796. [16] Wu J S, Hwang I, Kim K S, et al. Org. Lett., 2007, 9(5): 907. [17] YANG Xi, PAN Zu-ting, MA Yong, et al(杨 洗, 潘祖亭, 马 勇, 等). Journal of Analytical Chemistry(分析化学学报), 2003, 19(6): 588. [18] Zhang X, Shiraishi Y, Hirai T. Tetrahedron Lett., 2007, 48: 5455. [19] Lee M H, Wu J S, Lee J W, et al. Org. Lett., 2007, 9: 2501. [20] YANG Man-man, YANG Pin, ZHANG Li-wei, et al(杨曼曼, 杨 频, 张立伟, 等). Chinese Science Bulletin(科学通报), 1994, 39(1): 374.
