Identification of Authentic and Fake Cigarettes Using Near Infrared Spectroscopy Combined with Principal Component Analysis-Mahalanobis Distance
ZHANG Ling-shuai1, WANG Wei-dong1, GU Yun-hong1, XING Jun2*
1. Henan Province Key Laboratory of Ion Beam Bio-engineering, Zhengzhou University, Zhengzhou 450052, China 2. China National Tobacco Quality Supervision & Test Centre, Zhengzhou 450001, China
Abstract:In order to discriminate fake and genuine cigarettes correctly and rapidly, cigarettes of brand A and fake cigarettes of brand A were scanned by the NIR spectrometer, and an identifying model was developed by near infrared spectroscopy combined with principal component-Mahalanobis distance pattern recognition method. The pretreated spectra data of cigarette samples were analyzed through principal component analysis (PCA), and the result of the analysis suggested that the accumulation of first 4 principal components was more than 97.46%. One hundred samples from total 120 cigarette samples were selected randomly. Then they were used to build qualitative discriminating model and the correlation coefficient was 0.95. Twenty unknown samples were validated by this model. The recognition rate is 100%. The model is reliable and practicable, and could be used as an assistant means for identifying fake and genuine cigarettes.
Key words:Near infrared spectroscopy;Cigarette;Principal component-mahalanobis distance;Identification;Authentic and fake
[1] HAN Liang-liang, MAO Pei-sheng, WANG Xin-guo, et al(韩亮亮,毛培胜,王新国,等). Journal of Infrared Millimeter Waves(红外与毫米波学报), 2008, 27(2): 86. [2] Mahesh S,Manickavasagan A, Jayas D S, et al. Biosystems Engineering, 2008, 101: 50. [3] Del Moral F G, Guillén A, Del Moral L G, et al. Journal of Food Engineering, 2009, 90(4): 540. [4] Alessandrini L, Romani S, Pinnavaia G, et al. Analytica Chimica Acta, 2008, 625(1): 95. [5] LIU De-yan, LUO Ji, CHEN Xing-miao(刘德燕,罗 吉,陈兴苗). Journal of Infrared Millimeter Waves(红外与毫米波学报), 2008, 27(2): 119. [6] WANG Li, HE Ying, WANG Yan-ping, et al(王 丽,何 鹰,王颜萍,等). Marine Environmental Science(海洋环境科学), 2004, 23(2): 58. [7] Blttner A,Marbach R,Heise H M. Journal of Molecular Strueture, 1995, 349. [8] Andreev G N, Schrader B, Schulz H, et al. Analytical Chemistry, 2001, 371: 1009. [9] Chen Yi, Xie Mingyong, Yan Yan, et al. Analytica Chimica Acta, 2008, 618(2): 121. [10] Dane A D, Rea G J, Walmsley A D, et al. Analytica Chimica Acta, 2001, 429(2): 185. [11] Zhang Yong, Cong Qian, Xie Yunfei, et al. Spectrochimica Acta Part A, 2008, 71(4): 1408. [12] ZHANG Jian-ping, CHEN Jiang-hua, SHU Ru-xin, et al(张建平,陈江华,束茹欣,等). China Tobacco Acta(中国烟草学报), 2007, 13(5): 1. [13] Shao Yongni, He Yong, Wang Yanyan. European Food Research and Technology, 2007, 224: 591. [14] Pizarro C. Analytica Chimica Acta, 2004, 509(1): 217.