Abstract:Sr2SiO4∶Eu2+, Nd3+ was synthesized by solid state synthesis method, and the sensitization of Nd3+ near-infrared luminescence by Eu2+ was investigated. The characteristic near-infrared luminescence of Nd3+ in Sr2SiO4 matrix was greatly enhanced by co-doping of Eu2+. The mechanism of energy transfer from Eu2+ to Nd3+ was analyzed through investigation of fluorescence excitation and emission spectra, and fluorescence lifetime. Excited Eu2+(Ⅱ) transfers energy effectively to Nd3+ through non-radiative energy transfer process in Sr2SiO4, resulting in greatly enhanced near-infrared luminescence of Nd3+, while sensitization of Nd3+ by Eu2+(Ⅰ) was achieved by the way of Eu2+(Ⅱ).
Key words:Solid state method;Sr2SiO4∶Eu2+;Nd3+;Near-infrared luminescence;Energy transfer
杨丽丽1,万文娇1,李锦清1,孟建新2* . Sr2SiO4∶Eu2+,Nd3+的近红外发光及Eu2+→Nd3+能量传递 [J]. 光谱学与光谱分析, 2011, 31(01): 43-46.
YANG Li-li1,WAN Wen-jiao1,LI Jin-qing1,MENG Jian-xin2* . Near-Infrared Fluorescence and Energy Transfer in Sr2SiO4∶Eu2+,Nd3+ . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(01): 43-46.
[1] Driesen K, Deun R V, Walrand C G, et al. Chemistry of Materials, 2004, 16: 1531. [2] Boyer J C, Manseau M P, Murray J I, et al. Langmuir, 2010, 26(2): 1157. [3] Nishi M, Tanabe S, Inoue M, et al. Optical Materials, 2005, 27: 655. [4] Sharma Y K, Surana S S L, Singh R K, et al. Optical Materials, 2007, 29: 598. [5] Amarie D, Alileche A, Dragnea B, et al. Analytical Chemistry, 2010, 82: 343. [6] Meng J X, Li J Q, Shi Z P, et al. Applied Physics Letters, 2008, 93: 221908. [7] Meng J X, Cheah K W, Shi Z P, et al. Applied Physics Letters, 2007, 91: 151107. [8] He H, Fu R L, Zhang X L, et al. Journal of Materials Science, 2009, 20: 433. [9] Qiao Y M, Zhang X B, Ye X, et al. Journal of Rare Earths, 2009, 27(2): 323. [10] Lakshminarasimhan N, Varadaraju U V. Materials Research Bulletin, 2008, 42: 2946. [11] Kim J S, Jeon P E, Choi J C, et al. Solid State Communications, 2005, 133: 187. [12] Sun X Y, Zhang J H, Zhang X, et al. Journal of Rare Earths, 2008, 26(3): 421. [13] Lee J H, Kim Y J. Materials Science and Engineering B, 2008, 146: 99.