1. 东北农业大学资源与环境学院,黑龙江 哈尔滨 150030 2. Faculty of Agriculture, Food and Environment, The Hebrew University of Jerusalem, Rehovot 76100, Israel
Cr(Ⅵ) Adsorption Mechanism on Rice Husk Ash Burned at Low Temperature by Method of IR Spectra
FAN Chun-hui1,ZHANG Ying1*,ZHANG Ying-chao1,LI Jing1,Benny Chefetz2
1. School of Resource & Environment, Northeast Agricultural University, Harbin 150030, China 2. Faculty of Agriculture, Food and Environment, The Hebrew University of Jerusalem, Rehovot 76100, Israel
Abstract:Boehm titration method was used to analyze functional groups on cell surface of rice husk ash burned at low temperature in the present paper. Effects of initial pH value and temperature on Cr(Ⅵ) adsorption were studied, adsorption capacity was tested with the help of kinetic models and adsorption isotherms, instruments of Fourier transform infrared spectroscopy(FTIR) and scanning electron microscope(SEM) were used to check characteristics and adsorption mechanism of Cr(Ⅵ). The results indicated that optimal removing rate was achieved at initial pH value 5, and pH values of aqueous solution changed little before and after adsorption process. The adsorbent of rice husk ash could remove Cr(Ⅵ) effectively, and the maximum removing rate could be 95% with Cr(Ⅵ) concentration 20 mg·L-1 and achieve 1-2 level of state standard(GB8978—1996). The adsorption process fits pseudo-second-order kinetic model and Langmuir isotherm better, the maximum adsorption capacity of Cr(Ⅵ) was 3.277 6 mg·g-1. Results of FTIR showed that amide Ⅱ band, Si—O—Si, O—Si—O were important for Cr(Ⅵ) removal. SEM micrographs revealed that series of needle-shaped precipitation appeared on cell surface, and inorganic precipitation mechanism and redox mechanism might work in the test. As a kind of low cost adsorbent, rice husk ash can be applied to remove heavy metals in environment with great potential.
[1] ZHAO Zhen-guo(赵振国). Adsorption Mechanism and Application(吸附作用应用原理). Beijing: Chemical Industry Press(北京: 化学工业出版社), 2005. 1. [2] Peternele W S, Winkler-Hechenleitner A A, Pineda E A G. Bioresource Technology, 1999, 68: 95. [3] Soylak M, Tuzen M. Journal of Hazardous Materials, 2006, 138: 195. [4] DAI Qun-wei, DONG Fa-qin, ZHANG Wei(代群威,董发勤,张 伟). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2009, 29(7): 1788. [5] Sullivan E J, Bowman R S, Legiee I A. Journal of Environment Quality, 2003, 32: 2387. [6] Shevade S, Ford R G. Water Research, 2004, 38: 3197. [7] Garg V K, Gupta R, Kumar R, et al. Bioresource Technology, 2004, 92(1): 79. [8] Amuda O S, Giwa A A, Bello I A. Biochemical Engineering Journal, 2007, 36: 174. [9] OUYANG Dong, CHEN Kai(欧阳东,陈 楷). Journal of Chinese Electron Microscopy Society(电子显微镜学报),2003, 22(5): 390. [10] State Environmental Protection Administration of China(国家环境保护总局). Monitoring and Analyzing Methods for the Examination of Water and Wastewater·4th ed(水和废水监测分析方法·第4版). Beijing: China Environmental Sciences Press(北京:中国环境科学出版社),2002. 346. [11] Boehm H P. Carbon, 1994, 32: 759. [12] Richard F C, Bourg A C M. Water Research, 1991, 25(7): 807. [13] Benguella B, Benaissa H. Water Research, 2002, 36: 2463. [14] Langmuir I. Journal of American Chemistry Society, 1918, 40: 1361. [15] LU Yong-quan, DENG Zhen-hua(卢涌泉,邓振华). Analysis of IR Spectra(实用红外光谱解析). Beijing: Publishing House of Electronics Industry(北京: 电子工业出版社), 1989. 21. [16] Strandberg G W, Shumate S E, Parrott J R. Applied and Environmental Microbiology,1981, 41: 237.