Abstract:2-hydroxy-4-methoxybenzo phenone (UV-9 ) is one of general auxiliary reagents used in paint resin and plastics, which can delay the material degradation and ageing of high polymer. Direct determination of high polymer by ultraviolet spectrum has not been reported. We selected an efficient solvent that can dissolve the resin of high polymer, and got an even,transparent and steady mensuration system. The first derivative absorption data of 2-hydroxy-4-methoxybenzo phenone(UV-9) were treated many times with smooth handing by Origin 6.1,a famous data analysis software. At a certain wavelength, the results accord with Beer′s law from 1.000 to 20.00 μg·mL-1, thus UV-9 can be measured directly. Its absorptivity is 5.7×104 L·mol-1·cm-1. The results of synthetic samples determined by this method showed that the relative standard deviation and the relative error of UV-9 are less than 5.25% and 4.75% respectively,and the UV-9 recovery rate is 98.88%-102.04%.
[1] Synthetic Materials Institute of the Ministry of Chemical Industry, Jin Hai Chemical Engineering Company Limited(化工部合成材料研究院,金海化工有限公司). The Application Manual for Preventing Polymer Aging(聚合物防老化实用手册). Beijing: Chemical Industry Press(北京:化学工业出版社),1999. 330. [2] YU Zhao-nian(虞兆年). Coatings Technology, the Second Fascicule(涂料工艺(第二分册)). Beijing: Chemical Industry Press(北京: 化学工业出版社),1996. 168. [3] GAO Qing-yu,LI Xiao-hong,LIU Zhi-guo(高青雨,李小红,刘治国). Acta Polymerica Sinica(高分子学报),2002,(2): 245. [4] LIU Lin,AN Pu-jie,WANG Jian-guo et al(刘 琳,安普杰,王建国等). Coatings Industry(涂料工业),2002,(2): 4. [5] AMU Guleng, WU Xiao-wei, MENG Gendalai(阿木古楞,吴晓薇,孟根达来). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2001,21(1): 84.