Abstract：Ming dynasty bar-tile from the archaeological site of Heijing (Lufeng of Yunnan Province, China ) was analyzed by Raman microscopy, Ｘ-ray diffraction and electron probe microscopy (EPMA). It was found that the major components of the tile are SiO2, besides moonstone(KAlSi3O8var.of K-orthoclase), Na-orthoclase(NaAlSi3O8)and an unknown mineral(Al, Fe)3(PO4,VO4)2(OH)3·8H2O etc. The studies revealed that the agglomerant temperature of the bar-tile reached up to 1 500 ℃, indicating that the agglomerant technology of ceramics of Yunnan in the Ming dynasty (before 17 century) already attained a high level. Raman microscopy proves especially excellent in studinｇ antiques. The results show that the facility and reliability of Raman spectroscopy，as a non-destructive unique technique, are suitable for the discrimination between moonstone and K-orthoclase within tile. No other technique tried was successful in its identification. This research demonstrates that only by combining several complementary techniques is possible to conduct comprehensive research on antiques.
Key words：Raman microscopy;Ming dynasty bar-tile;Agglomerant temperature
王怡林1，杨 群1，李朝真2 . 黑井明代瓦条的拉曼光谱研究[J]. 光谱学与光谱分析, 2004, 24(07): 823-825.
WANG Yi-lin1，YANG Qun1，LI Chao-zhen2 . Raman Spectroscopic Study of Ming Dynasty Bar-Tile from Heijing of Lufeng . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(07): 823-825.
[1] Clark Ｒ J H，Gibbs P J. J. Raman Spectrosc.，1997，28：99. [2] Clark Ｒ J H, Curri L, Henshaw G S et al. J. Raman Spectrosc.，1997，28：105. [3] Brooke C J, Edwards H G M，Tait J Ｋ F. J. Raman Spectrosc.，1999，30：429. [4] YANG Qｕn，ＷANG Yi-lin，ZHANG Penｇ-ｘianｇ et al(杨 群，王怡林，张鹏翔等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2001，21(4)：503. [5] YANG Qun, ＷANG Yi-lin(杨 群，王怡林). Journal of Chuｘionｇ Teachers’College(楚雄师专学报)，2000，15(3)：72. [6] ZHANG Jia-hua et al(张家华等). Yｕnnan Cultural Ｒelic(云南文物)，1999，(1)：11. [7] Ｗilliams Ｋ P J，Nelson J，Dｙer S. The Renishaw Ｒaman Database of Geoloｇical and Mineraloｇical Materials，Enｇland：Ｒenishaw P1c. Transdｕcer Sｙstems Divison，1997. [8] Zhejiang University et al(浙江大学等四所院校). The Ceramic Physicochemistry(硅酸盐物理化学). Beijing: China Building Press(北京：中国建筑出版社)，1980. 241. [9] RAO Dong-sheng(饶东生). The Ceramic Physicochemistry(硅酸盐物理化学). Beijing: Metallurgical Industry Press(北京：冶金工业出版社)，1980. 44. [10] HUANG Yｕn-lan，PENG Zi-chenｇ，YANG Zhao-ｑinｇ et al(黄允兰，彭子成，杨肇清等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，1997，17(6)：89.
