Self-Assembly and Characterization of Pt Nanoparticles by Electrochemistry and In-Situ FTIR Reflection Spectroscopy
CHEN Wei,SUN Shi-gang*
State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, Institute of Physical Chemistry, Xiamen University, Xiamen 361005,China
Abstract:Pt nanoparticles (Ptn) were prepared by chemical reduction method. The average dimension of Ptn is about 2.5 nm in diameter determined from TEM studies. The Pt nanoparticles were then self-assembled on massive Au substrate. The process of self-assembly was investigated with Fe(CN)4-/3-6 for redox probe reaction. The result showed that the dithiol assembled on Au surface is inactive for electron transfer. However after assembly of Pt nanoparticles on the dithiol, the Au/SS-Ptn electrode becomes conductive again for electron transfer. The adsorption of CO on the Pt nanoparticles self-assembled on Au substrate in 0.1 mol·L-1 H2SO4 was studied by using in situ FTIR reflection spectroscopy. IR absorption of linear and bridge bonded CO species was observed around 2 030 and 1 845 cm-1 respectively. IR absorption of twin bounded CO adsorbed on the Pt nanoparticles was also observed about 2 100 cm-1. The results illustrated that the IR absorption of CO adsorbed on the Pt nanoparticles has been significantly enhanced. The present study is devoted to revealing the intrinsic properties of self-assembly system of nanoparticles, and is of importance in applications of electrocatalysis as well.
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