光谱学与光谱分析
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FTIR遥测固体推进剂燃烧温度
李 燕,王俊德* ,孙秀云,周学铁
南京理工大学化学工化学院, 江苏 南京 210014
Combustion Temperature Measurement of Solid Propellant by Remote Sensing FTIR
LI Yan,WANG Jun-de* ,SUN Xiu-tun,ZHOU Xue-tie
College of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210014,China
摘要 : 应用遥感FTIR对固体推进剂燃烧火焰的温度进行了研究。遥感FTIR光谱仪在光谱分辨率为4 cm-1 时,连续收集燃烧火焰的发射光谱。分别利用分子基带转振光谱测温法,以及分子发射光谱最大强度谱线测温法,对燃烧温度进行了遥感实时测定。文中列出了两种方法测得的各时刻的火焰温度。结果表明,两种方法在测量快速、剧烈燃烧的火焰温度时,都是很可靠的方法,当火焰的燃烧比较稳定时,分子发射光谱最大强度谱线测温法更为简便、快速。
关键词 :红外发射光谱;遥感FTIR;温度测量;固体推进剂
Abstract :The combustion temperature of solid propellant was measured in this paper. Emission spectra of the combustion flame were collected with remote sensing FTIR at the resolution of 4 cm-1 . The combustion temperatures with the burning time were calculated from the maximum spectral line intensity and the molecular rotation-vibration spectra of HF molecule, respectively. Combustion temperatures at each time were all 1 788.8 K from the maximum spectral line intensity method. For comparison, the temperatures calculated from the molecular rotation-vibration spectra were 1 859.7,1 848.3, 1 804.0 and 1 782.7 K, respectively. Results show that the two methods are all dependable in measuring combustion temperature of solid propellant. But the maximum spectral line intensity method is more convenient and rapid than the other when the combustion is relatively stable.
Key words :Infrared emission spectra;Remote sensing FTIR;Temperature measurement;Solid propellant
收稿日期: 2002-11-16
修订日期: 2003-05-28
通讯作者:
王俊德
引用本文:
李 燕,王俊德* ,孙秀云,周学铁. FTIR遥测固体推进剂燃烧温度[J]. 光谱学与光谱分析, 2004, 24(08): 936-937.
LI Yan,WANG Jun-de* ,SUN Xiu-tun,ZHOU Xue-tie . Combustion Temperature Measurement of Solid Propellant by Remote Sensing FTIR . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(08): 936-937.
链接本文:
http://www.gpxygpfx.com/CN/Y2004/V24/I08/936
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