Study on the Adsorption Behavior of Ga, In and Tl on Nanometer-Size Titanium Dioxide by ICP-AES
HANG Yi-ping1,2, QIN Yong-chao1*, JIANG Zu-cheng1, HU Bin1
1.Wuhan University, College of Chemistry and Molecular Science, Wuhan 430072, China 2.Department of Applied Chemistry, Huanan University of Science and Technology, Guangzhou 510640, China
Abstract:The adsorption behavior of nanometer TiO2 towards Gallium (Ga) Indium (In) and Thallium (Tl) was investigated with inductively coupled plasma atomic emission spectrometry (ICP-AES).The optimum conditions for adsorption were studied in detail, and the test included sorption kinetics, effect of pH on adsorption ratio, enrichment factor, and adsorption capacity.Under the optimum conditions, Ga(Ⅲ) , In(Ⅲ) and Tl(Ⅰ) ions could be adsorbed and recovered quantitatively.The static adsorption capacities of Ga(Ⅲ), In(Ⅲ) and Tl(Ⅰ) on nanometer TiO2 were 48.6, 46.6 and 23.4 mg·g-1 respectively.For the elution of Ga(Ⅲ), In(Ⅲ) and Tl(Ⅰ), a mixture of 0.1 mol·L-1 EDTA solution and 1.0 mol·L-1 HNO3 was used, and the recovery ratio was above 92%.According to the definition of IUPAC, the detection limits (3σ) of this method for Ga, In and Tl with an enrichment factor of 12.5 are 3.0, 6.0 and 13 ng·mL-1, respectively; and relative standard deviations (RSD) are 1.85%, 1.96% and 3.4%, respectively (n=6).The proposed method has been applied successfully to the analysis of geological samples with satisfactory results.
杭义萍1,2,秦永超1*,江祖成1,胡 斌1 . ICP-AES研究纳米TiO2材料对Ga, In, Tl的吸附性能[J]. 光谱学与光谱分析, 2005, 25(07): 1131-1134.
HANG Yi-ping1,2, QIN Yong-chao1*, JIANG Zu-cheng1, HU Bin1 . Study on the Adsorption Behavior of Ga, In and Tl on Nanometer-Size Titanium Dioxide by ICP-AES . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(07): 1131-1134.
[1] LIU An-xi, ZHOU Zi-jun, LIU Wen-ying, et al(刘安喜, 周自军, 刘文英,等).Chinese Journal of Analytical Chemistry(分析化学), 1991, 19(2): 175. [2] GU Xue-xin, ZOU Hong, ZHU Ruo-hua, et al(谷学新, 邹 洪, 朱若华,等).Chinese Journal of Analysis Laboratory(分析试验室), 2001, 20(3): 96. [3] WANG Xu-dong, HE Xi-wen, GUO Hong-sheng, et al (王旭东, 何锡文, 郭洪声,等).Chinese Journal of Analytical Chemistry (分析化学), 2000, 28(7): 805. [4] LU Tie-cheng, LIN Li-bin, LIU Yan-zhang, et al (卢铁城, 林理彬, 刘彦章,等), Chinese J.of Materials Research(材料研究学报), 2001, 15(3): 291. [5] Cahn R W.Nature, 1988, 332: 112. [6] JIANG Hong-ji, LI Yan-feng, YE Zheng-fang, et al(姜鸿基, 李彦锋, 叶正芳,等).Chinese Journal of Functional Materials(功能材料), 2002, 33(4): 360. [7] LIU Yang-qiao, GAO Lian(刘阳桥, 高 濂).Chinese Journal of Inorganic Materials(无机材料学报), 2002, 17(6): 1292. [8] Vassileva E, Proinova I, Hadjiivanov K.Analyst, 1996, 121: 607. [9] Vassileva E, Hadjiivanov K, Stoychev T, et al.Analyst, 2000, 125: 693. [10] Liang P, Qing Y C, Hu B, et al.Anal.Chim.Acta, 2001, 440: 207. [11] Liang P, Qing Y C, Hu B, et al.Fresenius' J.Anal.Chem., 2000, 368: 638. [12] LIU Xue-feng, ZHANG Li, TU Ming-jing(刘雪峰,张 利,徐铭旌).Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005,25(2): 274. [13] ZAN Ling, ZHONG Jia-cheng, LUO Qi-rong(昝 菱, 钟家柽, 罗其荣).Chinese Journal of Inorganic Materials(无机材料学报), 1999, 14(2): 264. [14] DAI An-bang, YIN Jing-zhi, YAN Zhi-xian, ZHANG Qing-lian(戴安邦, 尹敬执, 严志弦, 张青莲).Inorganic Chemistry(the Last of Two Volume(无机化学教程·下册).Beijing: Publishing House of People Education(北京: 人民教育出版社),1972.576.