Abstract:Traditional Chinese medicine materials (TCM) contained abundant trace elements needed in human body. Mixed acid (HNO3∶HClO4) was added into samples treated by microwave digestion, and a systematic study was carried out by selection of the most appropriate working conditions and optimization of the sample mass. Some inorganic elements in 5 kinds of radix curcumae (Curcuma wenyujin Y. H. Chen et C. Ling, Curcuma longa L., Curcuma kwangsiensis S. G. Lee et C. F. Liang, Curcuma phaeocaulis Val. and Curcuma chuanyujin C. K.Hsieh et H. Zhang) necessary to lives were determined by flames atomic absorption spectrometry (AAS). Elements, such as K, Ca, Na, Mg, Zn, Fe, Cu and Mn were detected. The results show that there are similar elements in the five kinds of radix curcumae, while differences only exist in a few elements contents. The correlative analysis of trace elements in samples was carried out by cluster analysis of the 4 kinds of radix curcumae (Curcuma wenyujin Y. H. Chen et C. Ling, Curcuma longa L., Curcuma kwangsiensis S. G. Lee et C. F. Liang and Curcuma phaeocaulis Val.) in codex populations in a cluster, different from the unofficial sample (Curcuma chuanyujin C. K. Hsieh et H. Zhang). The cluster analysis results are consistent with the morphological characteristics of the traditional taxonomy results. The results showed that the analytic method is advisable. This paper provides scientific basis for deeply studing the relation between trace elements and drug effect of radix curcumae.
田玉梅,周丹,张玮,程存归*. 五种郁金无机元素比较及样品元素间相关性分析[J]. 光谱学与光谱分析, 2008, 28(09): 2192-2195.
TIAN Yu-mei,ZHOU Dan,ZHANG Wei,CHENG Cun-gui*. Comparison and Correlative Analysis of Trace Elements in Five Kinds of Radix Curcumae . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(09): 2192-2195.
[1] CAO Zhi-quan, SUN Zuo-min, SUN Ai-zhen(曹治权, 孙作民, 孙爱贞). Trace Elements and Traditional Chinese Medicine(无机元素与中医药). Beijing:China Press of Traditional Chinese Medicine(北京:中国中医药出版社),1993. 85. [2] CHENG Cun-gui,LI Dan-ting,LIU Xing-hai,et al(程存归,李丹婷,刘幸海,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006,26(1):156. [3] CHENG Cun-gui,HONG Qing-hong,LI Dan-ting,et al(程存归,洪庆红,李丹婷,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006,26(9):1735. [4] HU Hao-bin,CAO Hong,LIU Jian-xin,et al(胡浩斌,曹 宏,刘建新,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006,26(11):2130. [5] E Er-deng-sang,BAO Yin-da-lai,Na Ren-ge-rile(额尔登桑,宝音达来,娜仁格日乐). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006,26(11):2134. [6] Singh D K,Ray A R. Journal of Macromolecular Science-Reviews in Macromolecular Chemistry and Physics,2002,40(1):69. [7] The Official Committee of Hygine Department of the People’s Republic of China(中华人民共和国卫生部药典委员会编). Pharmacopoeia of the People’s Republic of China(中华人民共和国药典, 2005年). Beijing:Chemical Industral Press(北京: 化学工业出版社),2005. 144. [8] National Institute for the Control of Pharmaceutical and Biological Products,State Drug Administrate,P. R. China;Guangdong Provincial Institute for Drug Control(中国药品生物制品检定所,广东省药品检定所). Photo Album for Traditional Chinese Herbal Medicines and Their Confusable Varieties Identification (中国中药材真伪鉴别图典Ⅱ). Guangzhou:Guangdong Science and Technology Press (广州:广东科技出版社),1997. 148. [9] CHENG Cun-gui, SUN Cui-rong, PAN Yuan-jiang(程存归,孙翠荣,潘远江). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(9):1055. [10] LI Dan-ting, ZHANG Chang-jiang, WANG Jin, et al(李丹婷,张长江,汪 劲,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006,26(11):2024. [11] LI Dan-ting,CHENG Cun-gui, DU Zheng-xiong, et al(李丹婷,程存归,杜正雄,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006,26(12):2186. [12] WANG Hao,SUN Su-qin,XU Jin-wen,et al(王 昊,孙素琴,许锦文,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2003,23(2):253.