Determination of As in Industrial Wastewater by Laser-Induced Breakdown Spectroscopy
LIN Zhao-xiang1, CHANG Liang1,LI Jie2, LIU Lin-mei1
1. Laboratory for Laser Spectrum Research, South-Central University for Nationalities, Wuhan 430074, China 2. State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China
Abstract:The wastewater from industrial smelting process contains heavy metals such as arsenic (As) that produce serious environmental pollution and cause actual harm to the health of people. It is necessary to control the pollution at the source and achieve a real-time and online monitoring. The laser-induced breakdown spectroscopy (LIBS) is a new elemental analysis technique, and has the advantage of rapid detection. An LIBS setup has been established. The Nd∶YAG laser beam is focused onto the sample, then the plasmas are produced. The emission spectra of plasmas are dispersed by an Echelle spectrograph and detected by an intensified charge-coupled device (ICCD). Experiments have been carried out on the industrial wastewater collected from the scene. The spectral lines of As element were obtained. The calibration curve of the line intensities versus the concentrations of the As element was acquired by the experiment. The calibration curve can be used for the quantitative analysis of arsenic element with an unknown concentration in the industrial wastewater. The results showed that the LIBS technique can be applied in the rapid detection of As element in industrial wastewater, and has wide range of applications.
林兆祥1,常亮1,李捷2,刘林美1 . 应用激光诱导击穿光谱检测污水溶液中的砷[J]. 光谱学与光谱分析, 2009, 29(06): 1675-1677.
LIN Zhao-xiang1, CHANG Liang1,LI Jie2, LIU Lin-mei1 . Determination of As in Industrial Wastewater by Laser-Induced Breakdown Spectroscopy. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(06): 1675-1677.
[1] LONG Da-xiang(龙大祥). Industrial Water & Wastewater(工业用水与废水), 2000, 31(4): 30. [2] YING Hui(应 晖). Engineering Design and Construction(工程设计与建设), 2004, 36(2): 42. [3] YAO Guo, WANG Jian-wei(姚 国, 王建卫). Environmental Monitoring in China(中国环境监测), 2007, 23(5): 22. [4] Gruber J, Heitz J, Strasser H, et al. Spectrochimica Acta Part B, 2001, 56(6): 685. [5] Lithgow G A, Robinson A L, Buckley S G. Atmospheric Environment, 2004, 38(20): 3319. [6] Colao F, Fantoni R, Lazic V, et al. Planetary and Space Science, 2004, 52(1-3): 117. [7] Koch S, Court R, Garen W, et al. Spectrochimica Acta Part B, 2005, 60(7-8): 1230. [8] Alamelu D, Sarkar A, Aggarwal S K. Talanta, 2008, 77(1): 256. [9] Rai N K, Rai A K. Journal of Hazardous Materials, 2008, 150(3): 835. [10] ZHANG Wen-yan, LIN Zhao-xiang, SONG Shu-yan, et al(张文艳, 林兆祥, 宋述燕, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2008, 28(5): 1003. [11] LI Jie, LU Ji-dong, XIE Cheng-li, et al(李 捷, 陆继东, 谢承利, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2008, 28(4): 736. [12] SONG Dong-ting, QI Hong-xing, SHU Rong(宋冬婷, 亓洪兴, 舒 嵘). Infrared(红外), 2007, 28(9): 19. [13] TANG Xiao-shuan, LI Chun-yan, ZHU Guang-lai, et al(唐晓闩, 李春燕, 朱光来, 等). Chinese Journal of Lasers(激光), 2004, 31(6): 687. [14] SONG Yi-zhong, LI Liang, ZHU Rui-fu(宋一中, 李 亮, 朱瑞富). Chinese Journal of Atomic and Molecular Physics(原子与分子物理学报), 2000, 17(4): 589. [15] NIST electronic database, at http://physics.nist.gov/PhysRefData.