Abstract：New N-benzoin aniline and Eu(BZA)3phen were synthesized, and they were characterized by EA, IR，1H NMR and UV. The Eu(Ⅲ) complex spectra were excited at the wavelength of 342 nm, which exhibited a red emissive color, and the Eu characteristic peaks appeared at 592 and 615 nm, respectively. The 615 nm transition showed the strongest emission. N-benzoin aniline sensitizes to Eu ions and it is a good ligand of Eu complex.
[1] Liang C J, Hong Z R, Liu X Y, et al. Thin Solid Films, 2000, 359: 14. [2] Jiang Xuezhong, Alex K Y Jen, Greg D Phelan, et al. Thin Solid Films, 2002, 416: 212. [3] Zheng Youxuan, Liang Yujun, Zhang Honjie, et al. Mater. Lett., 2002, 53: 52. [4] Gao Deqing, Bian Zuqiang, Wang Kezhi, et al. J. of Alloys and Compounds, 2003, 358: 188. [5] PEI Yian, WANG Xiao-lin, YU Wang-lin, et al. Macromolecules, 2002, 35: 7277. [6] XIAO Zun-hong，TAN Song-ting，ZHOU Hong-bo, et al(肖尊宏, 谭松庭, 周洪波, 等). J. of the Chinese Rare Earth Society(中国稀土学报)，2002，20(6)：667. [7] HUANG Ling，HUANG Chun-hui(黄 玲, 黄春辉). Acta Chimica Sinica(化学学报)，2000，58(12)：1493. [8] XIAO Zun-hong，TAN Song-ting，ZOU Ying-ping, et al(肖尊宏, 谭松庭, 邹应萍, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2004，24(1)：18. [9] XIAO Zun-hong(肖尊宏). Chinese Chemical Reagents(化学试剂)，2005，27(5)：292. [10] WANG Lian-hui, WANG Wen, ZHANG Wen-gong, et al，Chem. Mater., 2000, 12: 2212. [11] Yu Gui, Liu Yunqi, Wu Xia, et al. Chem. Mater., 2000, 12: 2537. [12] Zhong Guolun, Kyungkon Kim, et al. Synth. Met., 2002，129: 193. [13] Ling Qidan, Yang Mujie, Wu Zhefu, et al. Polymer, 2001, 42: 4605. [14] ZHONG Chao-fan, DENG Jian-cheng, TONG Jue, et al(钟超凡, 邓建成, 童 珏, 等). J. of Chinese Inorganic Chemistry(无机化学学报)，1996，12(3): 167.
