Simultaneous Determination of Trace Arsenic and Antimony in Textile by Intermittent Flow-Hydride Generation-Atomic Fluorescence Spectrometry with L-Cysteine as a Prereducer
Lü Shui-yuan, DAI Jin-lan, ZHONG Mao-sheng
Fujian Entry-Exit Inspection and Quarantine Bureau, Fuzhou 350001, China
Abstract：A method for the simultaneous determination of trace arsenic and antimony in textile by intermittent flow-hydride generation-atomic fluorescence spectrometry with L-cysteine as a prereducer was developed. The optimal instrument condition was established. The influence factors such as the acidity of sample solution and carrier liquid, the concentrations of KBH4 and L- cysteine, the flow rate of carrier, and the interference of coexistent elements were investigated. The method was convenient and rapid. Under the optimal condition, the detection limits were 0.35 and 0.22 μg·L-1, the relative standard deviations were 1.3% and 2.8%, and the recoveries were in the ranges of 93.6%-98.4% and 92.2%-103.6% for As and Sb respectively.
吕水源,戴金兰,钟茂生. L-半胱氨酸预还原断续流动-HG-AFS法同时测定纺织品中微量砷和锑 [J]. 光谱学与光谱分析, 2006, 26(07): 1352-1355.
Lü Shui-yuan, DAI Jin-lan, ZHONG Mao-sheng. Simultaneous Determination of Trace Arsenic and Antimony in Textile by Intermittent Flow-Hydride Generation-Atomic Fluorescence Spectrometry with L-Cysteine as a Prereducer . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(07): 1352-1355.
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