The IR Spectra of Complexes of 2-Hydroxy-2-Ferrocenylpropylamine with Ni(Ⅱ), Cu(Ⅱ), Zn(Ⅱ), Cd(Ⅱ) and Hg(Ⅱ)
WANG Xiao-li1,2, BIAN Zhan-xi1*, WANG Xi-gui2
1. College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot 010021, China 2. Chemistry and Environment Science College of Inner Mongolia Normal University, Huhhot 010022, China
Abstract：α-cyano-α-ferrocenylethoxytrimethylsilame was prepared by the addition of trimethysilyl cyanide to acetylferrocene. 2-Hydroxy-2-ferrocenylpropylamine(FcA) was synthesized by the reduction of α-cyano-α-ferrocenylethoxytrimethylsilame with lithium aluminum hydride. A series of coordinate complexes—FcA-Ni(Ⅱ), FcA-Cu(Ⅱ), FcA-Zn(Ⅱ), FcA-Cd(Ⅱ) and FcA-Hg(Ⅱ) were obtained through coordination of this ligand with MCl2(M=Ni, Cu, Zn, Cd and Hg). The FTIR spectra of the complexes and ligand were obtained in the range of 4 000-400 cm-1. Their major bands were assigned and compared. The results showed that in all complexes some bands(νO—H, νN—H, δO—H, δN—H) were shifted to lower wave number, and some(νC—N, νO—N) were shifted to higher wave number. The aminoalcohol groups and metal ions were bound with coordinated bond.
Key words：Ferrocenylaminoalcohol;Coordinate metal complexes;FTIR
王晓丽1,2,边占喜1*,王喜贵2. 2-羟基-2-二茂铁基丙胺与Ni(Ⅱ), Cu(Ⅱ), Zn(Ⅱ), Cd(Ⅱ), Hg(Ⅱ)配合物的红外光谱研究[J]. 光谱学与光谱分析, 2006, 26(06): 1054-1056.
WANG Xiao-li1,2, BIAN Zhan-xi1*, WANG Xi-gui2. The IR Spectra of Complexes of 2-Hydroxy-2-Ferrocenylpropylamine with Ni(Ⅱ), Cu(Ⅱ), Zn(Ⅱ), Cd(Ⅱ) and Hg(Ⅱ). SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(06): 1054-1056.
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