Abstract:Surface enhanced Raman scattering spectra of phytic acid were recorded in the sol oxide silver. Based on ab-initio/STO-3 quantum calculations results, assignments to the vibrational modes of phytic acid were carried out. On the basis of the mechanism of SERS, the adsorption modes were suggested that phytic acid chemically adsorbed on the oxide silver surface through four phosphate bonds.
封婕,孙晓靖,朱筠,夏微,刘泓,杨海峰* . 植酸在氧化银溶胶中的表面增强拉曼光谱[J]. 光谱学与光谱分析, 2006, 26(05): 858-860.
FENG Jie, SUN Xiao-jing, ZHU Jun, XIA Wei, LIU Hong, YANG Hai-feng*. Surface Enhanced Raman Scattering Spectra of Phytic Acid in the Sol Silver Oxide. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(05): 858-860.
[1] ZHANG Hong-sheng, YANG Xiao-lei, CHEN Xi(张洪生, 杨小蕾, 陈 熹). Chinese J. of Corrosion Sci. and Protection Techn.(腐蚀科学与防护技术), 2002, 14: 243. [2] Baba H, Kodama T, Fujii T. Boshoku Gijutsu., 1985, 34: 10. [3] Yamamoto H, Ota Y. Japanese Patent, Japanese Kokai Tokkyo Koho JP 60 194, 088[85 194 088], (1985), Chem. Abst. 1986, 104: 114558j. [4] Fleischmann M, Hendrz P J, McQuillan A. J. Chem. Phys. Lett.,1974, 26: 163. [5] Nie S M, Emory S R. Science,1997, 273: 21. [6] GU Ren-ao, CAO Wen-dong, CAO Pei-gen, et al(顾仁敖, 曹文东, 曹佩根, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001, 21(3): 308. [7] Li Yingsing, Cheng Jingcai, Coons Lewis B. Spectrochimica Acta(Part A), 1999, 55: 1197. [8] Olson Lin Lydia G, Lo Yu-Shui, Beebe Thomas P. Anal.Chem., 1999, 71: 596. [9] Lee P C, Meisel D. J. Physical Chemistry, 1982, 86: 3391. [10] Creighton J A, Blatchford C G, Albrecht M G. J. Am. Chem. Soc. Faraday Trans., 1980, 75: 790. [11] Chumannov G D, Efremov R G, Nabiev I R. J. Raman Spectroscopy, 1990, 21: 43. [12] Yang Hai-feng, Feng Jie, Liu Yan-li, et al. J. Phys. Chem. B, 2004, 108: 17412. [13] Creighton J. In: Spectroscopy of Surface, Eds. Clark R, Hestere R. London: John Willey and Sons Ltd, 1988. 37. [14] KE Wei-zhong WU Jian-zhong(柯惟中, 吴缄中). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(5): 551. [15] WANG Yu, LI Ying-sing, ZHANG Zheng-xing, et al(王 玉, LI Ying-sing, 张正行,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(11): 1376.