关键词:激光诱导荧光(LIF);特征光谱荧光标记(SFS);最小二乘法-Gaussian拟合;溶解有机物(DOM);叶绿素a(Chl a)
Abstract:A sort of analytical method of fast diagnosis of organic matter in water is discussed. The total luminescence spectra (TLS) of water samples in combination with laser induced fluorescence (LIF) measurements using 532 nm wavelength excitation source were measured in the laboratory. The spectra of dissolved organic matter (DOM) and chlorophyll a (Chl a) were pointed out and obtained with spectral fluorescence signature (SFS) technique. The spectrum of water Raman scattering and fluorescence of DOM and Chl a were separated from TLS with fiting Gaussian of the least squares method, and a high correlation coefficient excelling 0.996 4 was obtained. The results indicated the possibilities of water quality monitoring in real time and on line based upon SFS technique and fitting Gaussian of the least squares method.
Key words:Laser induced fluorescence (LIF);Spectral fluorescence signature (SFS);Fitting Gaussian of the least squares method;Dissolved organic matter (DOM);Chlorophyll a (Chl a)
赵南京,刘文清,崔志成,张玉均,刘建国,李宏斌,杨立书 . 利用特征光谱荧光标记与高斯拟合分析水体中有机物的特性[J]. 光谱学与光谱分析, 2006, 26(05): 922-924.
ZHAO Nan-jing, LIU Wen-qing, CUI Zhi-cheng, ZHANG Yu-jun, LIU Jian-guo, LI Hong-bin, YANG Li-shu . Analysis of the Characters of Organic Matter in Water Using Spectral Fluorescence Signature and Fitting Gaussian . SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(05): 922-924.
[1] Bristow M, Nielsen D, Bundy D, et al. Appl. Opt., 1981, 20(17): 2889. [2] Hoge F E, Swift R N. Appl. Opt., 1981, 20(18): 3197. [3] ZHAO Nan-jing, LIU Wen-qing, LIU Jian-guo, et al(赵南京,刘文清,刘建国, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(7): 1077. [4] ZHAO Nan-jing, LIU Wen-qing, LI Hong-bin, et al(赵南京,刘文清,李宏斌, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(9): 1460. [5] Poryvkina L V, Babichenko S M, Lapimaa J. AMBIO, 1992, XXI(7): 465. [6] Dudelzak A E, Babichenko S M, Poryvkina L V, et al. Appl. Opt., 1991, 30:453. [7] Babichenko S M, Kaitala S, Leeben A, et al. Journal of Marine Systems, 1999, 23: 69. [8] Babichenko S M, Leeben A, Poryvkina L, et al. Journal of Environmental Monitoring, 2000, 2(4): 378. [9] Barbini R, Colao F, Fantoni R, et al. ICES Journal of Marine Science, 1998, 55: 793. [10] Drozdowska Violetta, Lisin Sergey. Ooeanologia, 2002, 44(3): 339. [11] Leonard D A, Chang C H. United State Patent:3806727, 1974, Apr. 23.