Abstract:The solid rare-earth complexes were synthesized using rare-earth ions (RE=Tb, Nd, Sm, La) reacting with ortho-amino phenylbenzoic acid (L) and 2,2’-bipyridine (bipy). Their compositions were confirmed and the spectral properties were characterized by element analysis, infrared and ultraviolet absorption spectra, and DTA-TGA. The fluorescent properties of complexes TbL3 and TbL3·bipy·3H2O were also measured and discussed. The result shows that the fluorescence intensity of TbL3·bipy·3H2O is stronger than that of TbL3.
王少亭,杨永丽,朱惠菊,聂峰梅,宗瑞发,邓玉恒* . 稀土、2,2’-联吡啶、邻氨基苯基苯甲酸配合物合成、光谱表征及荧光性质[J]. 光谱学与光谱分析, 2006, 26(05): 933-935.
WANG Shao-ting, YANG Yong-li, ZHU Hui-ju, NIE Feng-mei, ZONG Rui-fa, DENG Yu-heng* . Synthesis and Spectral Characterization of Rare-Earth-Ortho-Amino Phenylbenzoate-2,2’-Bipyridine Complexes. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(05): 933-935.
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